img
Diaquabis(N,N-diethylnicotinamide-κN1)bis(4-formylbenzoato-κO1)zinc         
Yazarlar
Doç. Dr. Mustafa SERTÇELİK Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye
Nagihan Delibaş
Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Özet
In the title complex, [Zn(C8H5O3) 2(C10H14N2O)2(H 2O)2], the ZnII cation is located on an inversion center and is coordinated by two 4-formyl-benzoate anions, two N,N-diethyl-nicotinamide (DENA) ligands and two water mol-ecules. The four O atoms in the equatorial plane around the ZnII cation form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 2.96 (11)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 79.26 (4)°. The coordinating water mol-ecule links with the carboxyl-ate group via an intra-molecular O-H⋯O hydrogen bond. In the crystal, O-H⋯O and weak C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular network. A π-π contact between the parallel pyridine rings of adjacent mol-ecules may further stabilize the crystal structure [centroid-centroid distance = 3.5654 (8) Å].
Anahtar Kelimeler
data-to-parameter ratio = 17.9 | mean σ(C-C) = 0.002 Å | R factor = 0.025 | single-crystal X-ray study | T = 100 K | wR factor = 0.081
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler ESCI
Makale Dili İngilizce
Basım Tarihi 08-2012
Cilt No 68
Sayı 8
Doi Numarası 10.1107/S1600536812031200
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S1600536812031200