Diaquabis(N,N-diethylnicotinamide-κN1)bis(4-formylbenzoato-κO1)zinc
Yazarlar (4)
Doç. Dr. Mustafa SERTÇELİK Kafkas Üniversitesi, Türkiye
Nagihan Aylakdeliba
Sakarya Üniversitesi, Türkiye
Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(Diğer hakemli uluslarası dergilerde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | ESCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2012 |
| Kabul Tarihi | 09-07-2012 | Yayınlanma Tarihi | 14-07-2012 |
| Cilt / Sayı / Sayfa | 68 / 8 / – | DOI | 10.1107/S1600536812031200 |
| Makale Linki | https://doi.org/10.1107/s1600536812031200 | ||
| Özet |
| In the title complex, [Zn(C8H5O3)2(C10H14N2O)2(H2O)2], the ZnII cation is located on an inversion center and is coordinated by two 4-formylbenzoate anions, two N,N-diethylnicotinamide (DENA) ligands and two water molecules. The four O atoms in the equatorial plane around the ZnII cation form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 2.96 (11)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 79.26 (4)°. The coordinating water molecule links with the carboxylate group via an intramolecular O—H⋯O hydrogen bond. In the crystal, O—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular network. A π–π contact … |
| Anahtar Kelimeler |
| data-to-parameter ratio = 17.9 | mean σ(C-C) = 0.002 Å | R factor = 0.025 | single-crystal X-ray study | T = 100 K | wR factor = 0.081 |
Science Direct
Diaquabis(N,N-diethylnicotinamide-κN1)bis(4-formylbenzoato-κO1)zinc
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 5 |
| Web of Science | 4 |
| Scopus | 4 |