Yazarlar |
İbrahim Göker Zaman
Türkiye |
Nagihan Delibaş
Sakarya Üniversitesi, Türkiye |
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Özet |
In the title centrosymmetric binuclear Cd II compound, [Cd 2(C 7H 5O 3) 4(C 6H 6N 2O) 2]·4H 2O, the six-coordinated Cd II atom is chelated by the carboxyl-ate groups of the two 3-hy-droxy-benzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxylate groups. In the crystal, O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π Contacts between the pyridine rings and between the benzene rings [centroid-centroid distances = 3.770 (1), 3.769 (1) and 3.632 (1) Å] may further stabilize the structure. |
Anahtar Kelimeler |
data-to-parameter ratio = 12.6 | mean σ(C-C) = 0.002 Å | R factor = 0.017 | single-crystal X-ray study | T = 100 K | wR factor = 0.043 |
Makale Türü | Özgün Makale |
Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
Dergi ISSN | 2056-9890 |
Dergi Tarandığı Indeksler | ESCI |
Makale Dili | İngilizce |
Basım Tarihi | 02-2012 |
Cilt No | 68 |
Sayı | 2 |
Doi Numarası | 10.1107/S160053681200219X |
Makale Linki | http://dx.doi.org/10.1107/s160053681200219x |