| Yazarlar (4) |
|
Kafkas Üniversitesi, Türkiye |
|
Sakarya Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Hacettepe Üniversitesi, Türkiye |
| Özet |
| In the title centrosymmetric binuclear Cd II compound, [Cd 2(C 7H 5O 3) 4(C 6H 6N 2O) 2]·4H 2O, the six-coordinated Cd II atom is chelated by the carboxyl-ate groups of the two 3-hy-droxy-benzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxylate groups. In the crystal, O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π Contacts between the pyridine rings and between the benzene rings [centroid-centroid distances = 3.770 (1), 3.769 (1) and 3.632 (1) Å] may further stabilize the structure. |
| Anahtar Kelimeler |
| data-to-parameter ratio = 12.6 | mean σ(C-C) = 0.002 Å | R factor = 0.017 | single-crystal X-ray study | T = 100 K | wR factor = 0.043 |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | Diğer hakemli uluslarası dergilerde yayınlanan tam makale |
| Dergi Adı |
|
| Dergi ISSN | 1600-5368 |
| Dergi Tarandığı Indeksler | ESCI |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2012 |
| Cilt No | 68 |
| Sayı | 2 |
| Doi Numarası | 10.1107/S160053681200219X |
| Makale Linki | http://dx.doi.org/10.1107/s160053681200219x |