| Yazarlar |
Ömür Aydın
Türkiye |
|
Nagihan Delibaş
Sakarya Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
| Özet |
| The asymmetric unit of the polymeric title compound, [Co(C 7H4IO2)2(H2O) 2] n , contains one CoII cation, two iodo-benzoate anions and two water molecules. One iodo-benzoate anion and one water molecule bridge adjacent Co cations, forming a polymeric chain running along the a axis, while the other iodo-benzoate anion and water molecule coordinate in a monodentate manner to the CoII cation, completing the slightly distorted octa-hedral geometry. In the two independent anionic ligands, the carboxyl-ate groups are twisted away from the attached benzene rings by 51.38 (18) and 39.89 (11)°, and the two benzene rings are nearly perpendicular to each other with a dihedral angle of 86.09 (10)°. Intra-molecular O - H⋯O hydrogen bonds between coordinating water molecules and adjacent carboxyl-ate O atoms help to stabilize the molecular structure. In the crystal, weak C - H⋯O hydrogen bonds link the polymeric chains into a three-dimentional supra-molecular network. © Aydn et al. 2012. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | Acta Crystallographica Section E Structure Reports Online |
| Dergi ISSN | 1600-5368 |
| Dergi Tarandığı Indeksler | Emerging Sources Citation Index |
| Makale Dili | İngilizce |
| Basım Tarihi | 05-2012 |
| Cilt No | 68 |
| Sayı | 5 |
| Sayfalar | 601 / 602 |
| Doi Numarası | 10.1107/S1600536812015115 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536812015115 |
| Atıf Sayıları | |
| WoS | 3 |
| SCOPUS | 3 |
