catena-Poly[[aqua(2-iodobenzoato-κO)cobalt(II)]-µ-aqua-µ-2-iodobenzoatoκ2O:O′]
Yazarlar (4)
Ömür Aydn
Kafkas Üniversitesi, Türkiye
Nagihan Çaylak Deliba
Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(Diğer hakemli uluslarası dergilerde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | Emerging Sources Citation Index | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2012 |
| Cilt / Sayı / Sayfa | 68 / 5 / – | DOI | 10.1107/S1600536812015115 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536812015115 | ||
| Özet |
| The asymmetric unit of the polymeric title compound, [Co(C 7H4IO2)2(H2O) 2] n , contains one CoII cation, two iodo-benzoate anions and two water molecules. One iodo-benzoate anion and one water molecule bridge adjacent Co cations, forming a polymeric chain running along the a axis, while the other iodo-benzoate anion and water molecule coordinate in a monodentate manner to the CoII cation, completing the slightly distorted octa-hedral geometry. In the two independent anionic ligands, the carboxyl-ate groups are twisted away from the attached benzene rings by 51.38 (18) and 39.89 (11)°, and the two benzene rings are nearly perpendicular to each other with a dihedral angle of 86.09 (10)°. Intra-molecular O - H⋯O hydrogen bonds between coordinating water molecules and adjacent carboxyl-ate O atoms help to stabilize the molecular structure. In the crystal, weak C - H⋯O hydrogen bonds link the polymeric chains into a three-dimentional supra-molecular network. © Aydn et al. 2012. |
| Anahtar Kelimeler |
Science Direct
catena-Poly[[aqua(2-iodobenzoato-κO)cobalt(II)]-µ-aqua-µ-2-iodobenzoatoκ2O:O′]
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 3 |
| SCOPUS | 3 |