trans Tetraaquabis isonicotinamide kN1 zinc bis 3 hydroxybenzoate tetrahydrate
Yazarlar (4)
Ibrahim Göker Zaman
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Nagihan Çaylak Delibaş
Sakarya Üniversitesi, Türkiye
Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(Diğer hakemli uluslarası dergilerde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | Scopus | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2013 |
| Kabul Tarihi | 06-03-2013 | Yayınlanma Tarihi | 04-02-2012 |
| Cilt / Sayı / Sayfa | 69 / 4 / – | DOI | 10.1107/S1600536813006466 |
| Makale Linki | doi:10.1107/S1600536812003911 | ||
| Özet |
| The asymmetric unit of the title compound, [Zn(C6H6N2O)2(H2O)4](C7H5O3)2·4H2O, contains half of the complex cation with the ZnII ion located on an inversion center, a 3-hydroxybenzoate counter-anion and two uncoordinating water molecules. Four water O atoms in the equatorial plane around the ZnII ion [Zn—O = 2.089 (2) and 2.128 (2) Å] form a slightly distorted square-planar arrangement and the distorted octahedral geometry is completed by the two N atoms [Zn—N = 2.117 (2) Å] from two isonicotinamide ligands. In the anion, the carboxylate group is twisted from the attached benzene ring at 9.0 (2)°. In the crystal, a three-dimensional hydrogen-bonding network, formed by classical O—H⋯O and N—H⋯O and weak C—H⋯O hydrogen bonds, consolidates the crystal packing, which exhibits π–π stacking between the benzene and pyridine rings, with centroid–centroid distances of 3.458 (2) and 3 … |
| Anahtar Kelimeler |
Science Direct
trans Tetraaquabis isonicotinamide kN1 zinc bis 3 hydroxybenzoate tetrahydrate
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 7 |
| Web of Science | 3 |
| Scopus | 6 |