Crystal structure and Hirshfeld surface analysis of aquabis(nicotinamide-κN1)bis(2,4,6-trimethylbenzoato-κ2O,O′)cadmium(II)
Yazarlar (3)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
Safiye Özkaya Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Crystallographic Communications | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | Emerging Sources Citation Index | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2018 |
| Cilt / Sayı / Sayfa | 74 / 1 / 245–251 | DOI | 10.1107/S2056989018001494 |
| Makale Linki | https://journals.iucr.org/e/issues/2018/02/00/xu5916/xu5916.pdf | ||
| Özet |
| The asymmetric unit of the title complex,[Cd (CHO)(CHNO)(HO)], contains one half of the complex mol-ecule, with the Cd cation and the coordinated water O atom residing on a twofold rotation axis. The Cd cation is coordinated in a bidentate manner to the carboxyl-ate O atoms of the two symmetry-related 2, 4, 6-tri-methyl-benzoate (TMB) anions and to the water O atom at distances of 2.297 (2), 2.527 (2) and 2.306 (3) Å to form a distorted penta-gonal arrangement, while the distorted penta-gonal-bipyramidal coordin-ation sphere is completed by the two pyridine N atoms of the two symmetry-related monodentate nicotinamide (NA) ligands at distances of 2.371 (3) Å in the axial positions. In the crystal, mol-ecules are linked inter-molecular NH⋯ O, OH⋯ O and CH⋯ O hydrogen bonds with (12),(8),(14),(16),(20),(22),(22),(16),(16) and (18) ring motifs, forming a three-dimensional architecture. The Hirshfeld surface analysis of the crystal structure indicates that the most important contri... |
| Anahtar Kelimeler |
| Cadmium(II) | Crystal structure | Nicotinamide derivatives | Transition metal complexes of benzoic acid |
| Atıf Sayıları | |
| Web of Science | 6 |
| Scopus | 2 |