Crystal structure and Hirshfeld surface analysis of diaquabis(N,N-diethylnicotinamide-κN1)bis(2,4,6-trimethylbenzoato-κO)manganese(II)
Yazarlar (3)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
Safiye Özkaya
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Crystallographic Communications | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | Emerging Sources Citation Index | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2018 |
| Cilt / Sayı / Sayfa | 74 / 1 / 422–427 | DOI | 10.1107/S2056989018003377 |
| Makale Linki | https://journals.iucr.org/e/issues/2018/04/00/xu5920/xu5920.pdf | ||
| Özet |
| In the title centrosymmetric complex, [Mn(C10H11O2)(2)(C10H14N2O)(2)(H2O)(2)], the Mn-II cation is located on an inversion centre. The four O atoms form a slightly distorted square-planar arrangement around the Mn-II cation, and the distorted octahedral coordination is completed by two pyridine N atoms at distances of 2.3289 (15) angstrom. The dihedral angle between the planar carboxylate group and the adjacent benzene ring is 87.73 (16)degrees, while the benzene and pyridine rings are oriented at a dihedral angle of 43.03 (8)degrees. In the crystal, the water molecules are involved in both intramolecular (to the non-coordinating carboxylate O atom) and intermolecular (to the amide carbonyl O atom) O-H center dot center dot center dot O hydrogen bonds. The latter lead to the formation of layers parallel to (100). These layers are further linked via weak C-H center dot center dot center dot O hydrogen … |
| Anahtar Kelimeler |
| crystal structure | manganese(II) | transition metal complexes of benzoic acid and nicotinamide derivatives |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 4 |
| SCOPUS | 4 |
| Google Scholar | 4 |