Crystal structure of bis(μ-3-nitrobenzoato)-κ sup3/sup iO/i , iO/i ′: iO/i κ sup3/sup iO/i : iO/i , iO/i ′-bis[bis(3-cyanopyridine-κ iN/i sup1/sup )(3-nitrobenzoato-κ sup2/sup iO/i , iO/i ′)cadmium]
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Nurcan Akduran
Sanaem, Türkiye
Azer Özen
Kafkas Üniversitesi, Türkiye
Doç. Dr. Güventürk UĞURLU
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Crystallographic Communications | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | ESCI: Emerging Sources Citation Index | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2017 |
| Cilt / Sayı / Sayfa | 73 / 1 / 413–416 | DOI | 10.1107/S2056989017002675 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S2056989017002675 | ||
| Özet |
| The asymmetric unit of the title compound, [Cd2(C7H4NO4)4(C6H4N2)4], contains one CdII atom, two 3-nitro-benzoate (NB) anions and two 3-cyano-pyridine (CPy) ligands. The two CPy ligands act as monodentate N(pyridine)-bonding ligands, while the two NB anions act as bidentate ligands through the carboxyl-ate O atoms. The centrosymmetric dinuclear complex is generated by application of inversion symmetry, whereby the CdII atoms are bridged by the carboxyl-ate O atoms of two symmetry-related NB anions, thus completing the distorted N2O5 penta-gonal-bipyramidal coordination sphere of each CdII atom. The benzene and pyridine rings are oriented at dihedral angles of 10.02 (7) and 5.76 (9)°, respectively. In the crystal, C - H...N hydrogen bonds link the mol-ecules, enclosing R 2 2(26) ring motifs, in which they are further linked via C - H...O hydrogen bonds, resulting in a three-dimensional network. In addition, π-π stacking inter-actions between parallel benzene rings and between parallel pyridine rings of adjacent mol-ecules [shortest centroid-to-centroid distances = 3.885 (1) and 3.712 (1) Å, respectively], as well as a weak C - H...π inter-action, may further stabilize the crystal structure. |
| Anahtar Kelimeler |
| benzoic acid | cadmium | crystal structure | transition metal complex |
Science Direct
Crystal structure of bis(μ-3-nitrobenzoato)-κ sup3/sup iO/i , iO/i ′: iO/i κ sup3/sup iO/i : iO/i , iO/i ′-bis[bis(3-cyanopyridine-κ iN/i sup1/sup )(3-nitrobenzoato-κ sup2/sup iO/i , iO/i ′)cadmium]
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 1 |
| SCOPUS | 2 |