Crystal structure of bis(μ-3-nitrobenzoato)-κ sup3/sup iO/i , iO/i ′: iO/i κ sup3/sup iO/i : iO/i , iO/i ′-bis[bis(3-cyanopyridine-κ iN/i sup1/sup )(3-nitrobenzoato-κ sup2/sup iO/i , iO/i ′)cadmium]

Hökelek, Tuncer; Akduran, Nurcan; Özen, Azer; UĞURLU, GÜVENTÜRK; NECEFOĞLU, HACALİ

doi:10.1107/S2056989017002675

Crystal structure of bis(μ-3-nitrobenzoato)-κ sup3/sup iO/i , iO/i ′: iO/i κ sup3/sup iO/i : iO/i , iO/i ′-bis[bis(3-cyanopyridine-κ iN/i sup1/sup )(3-nitrobenzoato-κ sup2/sup iO/i , iO/i ′)cadmium]

Yazarlar (5)

Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye

Nurcan Akduran Sanaem, Türkiye

Azer Özen Kafkas Üniversitesi, Türkiye

Doç. Dr. Güventürk UĞURLU Kafkas Üniversitesi, Türkiye

Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Acta Crystallographica Section E Crystallographic Communications
Dergi ISSN	2056-9890 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler	ESCI: Emerging Sources Citation Index
Makale Dili	İngilizce	Basım Tarihi	03-2017
Cilt / Sayı / Sayfa	73 / 1 / 413–416	DOI	10.1107/S2056989017002675
Makale Linki	http://journals.iucr.org/e/issues/2017/03/00/wm5366/wm5366.pdf

Özet

The asymmetric unit of the title compound, [Cd2(C7H4NO4)4(C6H4N2)4], contains one Cd^II atom, two 3-nitro-benzoate (NB) anions and two 3-cyano-pyridine (CPy) ligands. The two CPy ligands act as monodentate N(pyridine)-bonding ligands, while the two NB anions act as bidentate ligands through the carboxyl-ate O atoms. The centrosymmetric dinuclear complex is generated by application of inversion symmetry, whereby the Cd^II atoms are bridged by the carboxyl-ate O atoms of two symmetry-related NB anions, thus completing the distorted N2O5 penta-gonal-bipyramidal coordination sphere of each Cd^II atom. The benzene and pyridine rings are oriented at dihedral angles of 10.02 (7) and 5.76 (9)°, respectively. In the crystal, C - H...N hydrogen bonds link the mol-ecules, enclosing R 2 ²(26) ring motifs, in which they are further linked via C - H...O hydrogen bonds, resulting in a three-dimensional network. In addition, π-π stacking inter-actions between parallel benzene rings and between parallel pyridine rings of adjacent mol-ecules [shortest centroid-to-centroid distances = 3.885 (1) and 3.712 (1) Å, respectively], as well as a weak C - H...π inter-action, may further stabilize the crystal structure.

Anahtar Kelimeler

benzoic acid | cadmium | crystal structure | transition metal complex

Pdf İndir

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Web of Science	1

Crystal structure of bis(μ-3-nitrobenzoato)-κ sup3/sup iO/i , iO/i ′: iO/i κ sup3/sup iO/i : iO/i , iO/i ′-bis[bis(3-cyanopyridine-κ iN/i sup1/sup )(3-nitrobenzoato-κ sup2/sup iO/i , iO/i ′)cadmium]

Dergi Adı	Acta Crystallographica Section E-Crystallographic Communications
Yayıncı	International Union of Crystallography
Açık Erişim	Evet
ISSN	2056-9890
E-ISSN	2056-9890
CiteScore	1,2
SJR	0,197
SNIP	0,361

Crystal structure of bis(μ-3-nitrobenzoato)-κ sup3/sup iO/i , iO/i ′: iO/i κ sup3/sup iO/i : iO/i , iO/i ′-bis[bis(3-cyanopyridine-κ iN/i sup1/sup )(3-nitrobenzoato-κ sup2/sup iO/i , iO/i ′)cadmium]

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