Crystal structure and Hirshfeld surface analysis of aquabis(nicotinamide-κ iN/i sup1/sup )bis(2,4,6-trimethylbenzoato-κ iO/i )zinc
Yazarlar (4)
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Gülcin Sȩfiye Asķin
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
Safiye Ö Zkaya
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
|
||
| Dergi Adı | Acta Crystallographica Section E Crystallographic Communications | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | ESCI: Emerging Sources Citation Index | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2017 |
| Cilt / Sayı / Sayfa | 73 / 1 / 1348–1352 | DOI | 10.1107/S2056989017011690 |
| Makale Linki | http://journals.iucr.org/e/issues/2017/09/00/is5478/is5478.pdf | ||
| Özet |
| The asymmetric unit of the title complex, [Zn(C10H11O2)2(C6H6N2O)2(H2O)], contains one half of the complex molecule, and the ZnII cation and the water O atom lie on a twofold rotation axis. The ZnII cation is coordinated by two carboxylate O atoms of the two symmetry-related 2,4,6-trimethylbenzoate (TMB) anions and by the water O atom at distances of 2.0311 (16) and 2.076 (2) Å to form a slightly distorted trigonal–planar arrangement, while the distorted trigonal–bipyramidal coordination sphere is completed by the two pyridine N atoms of the two symmetry-related monodentate nicotinamide (NA) ligands at distances of 2.2066 (19) Å in the axial positions. In the crystal, molecules are linked via intermolecular N—H⋯O and O—H⋯O hydrogen bonds with R22(12), R33(10) and R33(16) ring motifs, forming a double-column structure running along the c-axis direction. The Hirshfeld surface analysis of the … |
| Anahtar Kelimeler |
| crystal structure | transition metal complex of benzoic acid and nicotinamide derivatives | zinc |
Science Direct
Crystal structure and Hirshfeld surface analysis of aquabis(nicotinamide-κ iN/i sup1/sup )bis(2,4,6-trimethylbenzoato-κ iO/i )zinc
| Atıf Sayıları | |
| Google Scholar | 4 |
| Web of Science | 4 |
| Scopus | 1 |