| Yazarlar |
Doç. Dr. Vedat ADIGÜZEL
Kafkas Üniversitesi, Türkiye |
Hasan Erge
Yüzüncü Yıl Üniversitesi, Türkiye |
|
Alişoğlu Vahid
Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
| Özet |
| The solubility and the physicochemical properties (density, viscosity) in the Na-Zn- Cl-H2O), (Na + Zn + H2PO2 + H 2O), (Na + Cl + H2PO2 + H2O), and (Zn + Cl + H2PO2 + H2O) ternaries, and in Na+, Zn2+/Cl-, (H2PO 2)-//H2O reciprocal quaternary systems at T = 273.15 K were investigated by using the isothermal method. The diagrams of ternary salts systems, (NaCl + ZnCl2 + H2O), (NaCl + NaH2PO2 + H2O), (NaH2PO2 + Zn(H2PO2)2 + H2O), (ZnCl 2 + Zn(H2PO2)2 + H2O), are plotted in figures 1-4. However, whole ions of reciprocal quaternary salt systems are plotted in figure 5. Additionally, the density and viscosity values of ternary systems vs. their corresponding composition values in weight per cent are plotted in figures 6-10. At the (i) (ZnCl2 + Zn(H 2PO2)2 + H2O), (ii) (NaCl + ZnCl2 + H2O), (iii) (NaCl + NaH2PO2 + H2O), (iv) (NaH2PO2 + Zn(H2PO 2)2 + H2O) ternary systems the solid phase compositions have been determined as: (i) Zn(H2PO2) 2 · H2O, Zn(H2PO2) 2, ZnCl2 · 2H2O, (ii) NaCl, 2NaCl · ZnCl2 · 2H2O, and ZnCl2 · 2H2O, (iii) NaCl and NaH2PO2 · H2O, (iv) Zn(H2PO2)2 · H 2O and NaH2PO2 · H2O, respectively. largest in comparison with those of other salts, occupied 70% of the general crystallization field. © 2014 Elsevier Ltd. All rights reserved. |
| Anahtar Kelimeler |
| Phase diagram | Solid phase synthesis | Phase transition | Hypophosphite |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | JOURNAL OF CHEMICAL THERMODYNAMICS |
| Dergi ISSN | 0021-9614 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 08-2014 |
| Cilt No | 75 |
| Sayı | 1 |
| Sayfalar | 35 / 44 |
| Doi Numarası | 10.1016/j.jct.2014.04.014 |
| Atıf Sayıları | |
| WoS | 23 |
| SCOPUS | 23 |
