Study of the solubility viscosity and density in Na Zn2 Cl H2O Na Zn2 H2PO2 H2O Na Cl H2PO2 H2O and Zn2 Cl H2PO2 H2O ternary systems and in Na Zn2 Cl H2PO2 H2O reciprocal quaternary system at 273 15 K
Yazarlar (4)
Doç. Dr. Vedat ADIGÜZEL
Kafkas Üniversitesi, Türkiye
Hasan Erge
Van Yüzüncü Yıl Üniversitesi, Türkiye
Vahit Alisoglu
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Chemical Thermodynamics | ||
| Dergi ISSN | 0021-9614 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2014 |
| Cilt / Sayı / Sayfa | 75 / 1 / 35–44 | DOI | 10.1016/j.jct.2014.04.014 |
| Özet |
| The solubility and the physicochemical properties (density, viscosity) in the Na-Zn- Cl-H2O), (Na + Zn + H2PO2 + H 2O), (Na + Cl + H2PO2 + H2O), and (Zn + Cl + H2PO2 + H2O) ternaries, and in Na+, Zn2+/Cl-, (H2PO 2)-//H2O reciprocal quaternary systems at T = 273.15 K were investigated by using the isothermal method. The diagrams of ternary salts systems, (NaCl + ZnCl2 + H2O), (NaCl + NaH2PO2 + H2O), (NaH2PO2 + Zn(H2PO2)2 + H2O), (ZnCl 2 + Zn(H2PO2)2 + H2O), are plotted in figures 1-4. However, whole ions of reciprocal quaternary salt systems are plotted in figure 5. Additionally, the density and viscosity values of ternary systems vs. their corresponding composition values in weight per cent are plotted in figures 6-10. At the (i) (ZnCl2 + Zn(H 2PO2)2 + H2O), (ii) (NaCl + ZnCl2 + H2O), (iii) (NaCl + NaH2PO2 + H2O), (iv) (NaH2PO2 + Zn(H2PO 2)2 + H2O) ternary systems the solid phase compositions have been determined as: (i) Zn(H2PO2) 2 · H2O, Zn(H2PO2) 2, ZnCl2 · 2H2O, (ii) NaCl, 2NaCl · ZnCl2 · 2H2O, and ZnCl2 · 2H2O, (iii) NaCl and NaH2PO2 · H2O, (iv) Zn(H2PO2)2 · H 2O and NaH2PO2 · H2O, respectively. largest in comparison with those of other salts, occupied 70% of the general crystallization field. © 2014 Elsevier Ltd. All rights reserved. |
| Anahtar Kelimeler |
| Phase diagram | Solid phase synthesis | Phase transition | Hypophosphite |
Science Direct
Study of the solubility viscosity and density in Na Zn2 Cl H2O Na Zn2 H2PO2 H2O Na Cl H2PO2 H2O and Zn2 Cl H2PO2 H2O ternary systems and in Na Zn2 Cl H2PO2 H2O reciprocal quaternary system at 273 15 K
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 23 |
| SCOPUS | 23 |