Crystal structure of diaquabis N N diethylnicotinamide N1 bis 2 4 6 trimethylbenzoato O1 cobalt II
Yazarlar (5)
Gülçin Şefiye Aşkın Hacettepe Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Safiye Özkaya Baku State University, Azerbaycan
Raziye Çatak Çelik
Aksaray Üniversitesi, Türkiye
Aksaray Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Crystallographic Communications | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | ESCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2016 |
| Kabul Tarihi | 10-03-2016 | Yayınlanma Tarihi | 15-03-2016 |
| Cilt / Sayı / Sayfa | 72 / 1 / 498–501 | DOI | 10.1107/S2056989016004059 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S2056989016004059 | ||
| Özet |
| The centrosymmetric molecule in the monomeric title cobalt complex, [Co(C10H11O2)(2) (C10H14N2O)(2)(H2O)(2)], contains two water molecules, two 2,4,6-trimethylbenzoate (TMB) ligands and two diethylnicotinamide (DENA) ligands. All ligands coordinate to the Co-II atom in a monodentate fashion. The four O atoms around the Co-II atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination sphere completed by two pyridine N atoms of the DENA ligands. The dihedral angle between the planar carboxylate group and the adjacent benzene ring is 84.2 (4)degrees, while the benzene and pyridine rings are oriented at a dihedral angle of 38.87 (10)degrees. The water molecules exhibit both intramolecular (to the non-coordinating carboxylate O atom) and intermolecular (to the amide carbonyl O atom) O-H center dot center dot center dot O hydrogen bonds. The latter lead to … |
| Anahtar Kelimeler |
| Cobalt(II) | Crystal structure | Transition metal complexes of benzoic acid and nicotinamide derivatives |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 3 |
| Web of Science | 1 |
| Scopus | 1 |