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Crystal structure of trans diaquabis 4 cyanobenzoato O bis N N diethylnicotinamide N zinc II       
Yazarlar
Nurcan Akduran
Türkiye
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Ömer Aydoğdu
Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Özet
In the title complex, [Zn(C8H4NO2)2 (C10H14N2O)2 (H2O)2], the ZnII cation, located on an inversion centre, is coordinated by two water molecules, two 4-cyanobenzoate (CB) anions and two diethylnicotinamide (DENA) ligands in a distorted N2O4 octahedral geometry. In the molecule, the dihedral angle between the planar carboxylate group and the adjacent benzene ring is 9.50 (14)°, while the benzene and pyridine rings are oriented at a dihedral angle of 56.99 (5)°. The water molecules exhibit both an intramolecular hydrogen bond [to the non-coordinating carboxylate O atom, enclosing an S(6) hydrogen-bonding motif, where O⋯O = 2.6419 (19) Å] and an intermolecular hydrogen bond [to the amide carbonyl O atom, enclosing an R 2 2(16) ring motif, where O⋯O = 2.827 (2) Å]; the latter lead to the formation of supramolecular chains propagating along the [110] direction.
Anahtar Kelimeler
crystal structure | zinc complex | benzoate | nicotinamide derivatives
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler ESCI: Emerging Sources Citation Index
Makale Dili İngilizce
Basım Tarihi 10-2016
Cilt No 72
Sayı 10
Sayfalar 1374 / 0
Doi Numarası 10.1107/S2056989016013815
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S2056989016013815