Crystal structure of trans diaquabis 4 cyanobenzoato O bis N N diethylnicotinamide N zinc II
Yazarlar (4)
Prof. Dr. Nurcan Akduran Sanaem, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Dr. Öğr. Üyesi Ömer AYDOĞDU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Crystallographic Communications | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | ESCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2016 |
| Kabul Tarihi | 29-08-2016 | Yayınlanma Tarihi | 05-09-2016 |
| Cilt / Sayı / Sayfa | 72 / 1 / 1374–1376 | DOI | 10.1107/S2056989016013815 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S2056989016013815 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| In the title complex, [Zn(C8H4NO2)2(C10H14N2O)2(H2O)2], the ZnII cation, located on an inversion centre, is coordinated by two water molecules, two 4-cyanobenzoate (CB) anions and two diethylnicotinamide (DENA) ligands in a distorted N2O4 octahedral geometry. In the molecule, the dihedral angle between the planar carboxylate group and the adjacent benzene ring is 9.50 (14)°, while the benzene and pyridine rings are oriented at a dihedral angle of 56.99 (5)°. The water molecules exhibit both an intramolecular hydrogen bond [to the non-coordinating carboxylate O atom, enclosing an S(6) hydrogen-bonding motif, where O⋯O = 2.6419 (19) Å] and an intermolecular hydrogen bond [to the amide carbonyl O atom, enclosing an R22(16) ring motif, where O⋯O = 2.827 (2) Å]; the latter lead to the formation of supramolecular chains propagating along the [110] direction. |
| Anahtar Kelimeler |
| benzoate | crystal structure | nicotinamide derivatives | zinc complex |
Science Direct
Crystal structure of trans diaquabis 4 cyanobenzoato O bis N N diethylnicotinamide N zinc II
BM Sürdürülebilir Kalkınma Amaçları
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