| Yazarlar |
Nurcan Akduran
Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Ömer Aydoğdu
Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
| Özet |
| In the title complex, [Zn(C8H4NO2)2 (C10H14N2O)2 (H2O)2], the ZnII cation, located on an inversion centre, is coordinated by two water molecules, two 4-cyanobenzoate (CB) anions and two diethylnicotinamide (DENA) ligands in a distorted N2O4 octahedral geometry. In the molecule, the dihedral angle between the planar carboxylate group and the adjacent benzene ring is 9.50 (14)°, while the benzene and pyridine rings are oriented at a dihedral angle of 56.99 (5)°. The water molecules exhibit both an intramolecular hydrogen bond [to the non-coordinating carboxylate O atom, enclosing an S(6) hydrogen-bonding motif, where O⋯O = 2.6419 (19) Å] and an intermolecular hydrogen bond [to the amide carbonyl O atom, enclosing an R 2 2(16) ring motif, where O⋯O = 2.827 (2) Å]; the latter lead to the formation of supramolecular chains propagating along the [110] direction. |
| Anahtar Kelimeler |
| crystal structure | zinc complex | benzoate | nicotinamide derivatives |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Dergi Tarandığı Indeksler | ESCI: Emerging Sources Citation Index |
| Makale Dili | İngilizce |
| Basım Tarihi | 10-2016 |
| Cilt No | 72 |
| Sayı | 10 |
| Sayfalar | 1374 / 1376 |
| Doi Numarası | 10.1107/S2056989016013815 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S2056989016013815 |
| Atıf Sayıları | |
| WoS | 1 |
| SCOPUS | 2 |
| ResearchGate | 2 |
