Crystal structure of trans diaquabis 4 cyanobenzoato O bis N N diethylnicotinamide N cadmium
Yazarlar (5)
Nurcan Akduran Sanaem, Türkiye
Doç. Dr. Mustafa SERTÇELİK Kafkas Üniversitesi, Türkiye
Ömer Aydoğdu Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Crystallographic Communications | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | ESCI: Emerging Sources Citation Index | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2016 |
| Cilt / Sayı / Sayfa | 72 / 1 / 1827–1829 | DOI | 10.1107/S2056989016018247 |
| Makale Linki | http://journals.iucr.org/e/issues/2016/12/00/wm5339/wm5339.pdf | ||
| Özet |
| The mononuclear title cadmium complex, [Cd(C10H14N2O)2(C8H4NO2)2(H2O)2], is centrosymmetric and contains two water molecules, two 4-cyanobenzoate (CB) ligands and two diethylnicotinamide (DENA) ligands. All the ligands are coordinated to the CdII atom in a monodentate mode. The four nearest O atoms around the CdII atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination sphere being completed by the two pyridine N atoms of the DENA ligands at distances of 2.3336(13)Å. The dihedral angle between the carboxylate group and the adjacent benzene ring is 8.75(16)°, while the benzene and pyridine rings are oriented at a dihedral angle of 57.83(5)°. The water molecules exhibit both intramolecular [to the non-coordinating carboxylate O atom, enclosing an S(6) hydrogen-bonding motif, where O⋯O = 2.670(2)Å] and intermolecular [to the amide carbonyl O atom, enclosing an R 2 2(16) ring motif, where O⋯O = 2.781(2)Å] O - H⋯O hydrogen bonds. The latter lead to the formation of supramolecular chains propagating along [110]. |
| Anahtar Kelimeler |
| crystal structure | cadmium | transition metal complexes of benzoic acid and nicotinamide derivatives |
Science Direct
Crystal structure of trans diaquabis 4 cyanobenzoato O bis N N diethylnicotinamide N cadmium
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 2 |
| SCOPUS | 3 |