Crystal structure of diaquabis 4 tert butylbenzoato O bis nicotinamide N1 cobalt II dihydrate
Yazarlar (5)
Gülçin Şefiye Aşkın Hacettepe Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Safiye Özkaya
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Raziye Çatak Çelik
Aksaray Üniversitesi, Türkiye
Aksaray Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Crystallographic Communications | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | ESCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2016 |
| Kabul Tarihi | 30-05-2016 | Yayınlanma Tarihi | 03-06-2016 |
| Cilt / Sayı / Sayfa | 72 / 1 / 888–891 | DOI | 10.1107/S2056989016008689 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S2056989016008689 | ||
| Özet |
| The asymmetric unit of the mononuclear cobalt complex, [Co(C11H13O2)2(C6H6N2O)2(H2O)2]·2H2O, contains one half of the complex molecule, one coordinating and one non-coordinating water molecule, one 4-tert-butylbenzoate (TBB) ligand and one nicotinamide (NA) ligand; the Co atom lies on an inversion centre. All ligands coordinating to the Co atom are monodentate. The four nearest O atoms around the Co atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination completed by the two pyridine N atoms of the NA ligands at distances of 2.1638 (11) Å. The coordinating water molecules are hydrogen bonded to the carboxyl O atoms [O ⋯ O = 2.6230 (17) Å], enclosing an S(6) hydrogen-bonding motif, while intermolecular O—H⋯O hydrogen bonds link two of the non-coordinating water molecules to the coordinating water molecules and NA anions. The dihedral … |
| Anahtar Kelimeler |
| Benzoic acid | Cobalt(II) | Crystal structure | Nicotinamide | Transition metal complexes |
| Atıf Sayıları | |
| Google Scholar | 5 |
| Web of Science | 3 |
| Scopus | 3 |