Crystal structure of trans diaquabis nicotinamide N1 bis 4 nitrobenzoato O manganese II
Yazarlar (5)
Gülçin Şefiye Aşkın
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Ali Murat Tonbul
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Nefise Dilek
Aksaray Üniversitesi, Türkiye
Aksaray Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Crystallographic Communications | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | ESCI: Emerging Sources Citation Index | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2016 |
| Cilt / Sayı / Sayfa | 72 / 1 / 656–658 | DOI | 10.1107/S2056989016005612 |
| Makale Linki | http://journals.iucr.org/e/issues/2016/05/00/is5449/is5449.pdf | ||
| Özet |
| The asymmetric unit of the title compound, [Mn(C7H4NO4)2(C6H6N2O)2(H2O)2], contains one MnII atom, one 4-nitrobenzoate (NB) anion, one nicotinamide (NA) ligand and one water molecule; NA and NB each act as a monodentate ligand. The MnII atom, lying on an inversion centre, is coordinated by four O atoms and two pyridine N atoms in a distorted octahedral geometry. The water molecules are hydrogen bonded to the carboxylate O atoms. The dihedral angle between the carboxylate group and the adjacent benzene ring is 24.4 (3)°, while the benzene and pyridine rings are oriented at a dihedral angle of 86.63 (11)°. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the molecules, forming a layer parallel to the ab plane. The layers are further linked via weak C—H⋯O hydrogen bonds, a π–π stacking interaction [centroid–centroid distance = 3.868 (2) Å] and a weak C—H⋯π interaction, resulting … |
| Anahtar Kelimeler |
| crystal structure | manganese(II) | nicotinamide | 4-nitrobenzoic acid | transition metal complex |
Science Direct
Crystal structure of trans diaquabis nicotinamide N1 bis 4 nitrobenzoato O manganese II
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 1 |
| Google Scholar | 2 |