| Yazarlar |
Nurcan Akduran
Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Ömer Aydoğdu
Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
| Özet |
| The asymmetric unit of the title polymeric compound, [Cu(C8H4NO2)2(C10H14N2O)(H2O)]n, contains one CuII atom, one coordinating water molecule, two 4-cyanobenzoate (CB) ligands and one coordinating N,N-diethylnicotinamide (DENA) molecule. The DENA ligand acts as a bis-monodentate ligand, while the CB anions are monodentate. Two O atoms of the CB ligands, one O atom of the water molecule and the pyridine N atom of the DENA ligand form a slightly distorted square-planar arrangement around the CuII atom which is completed to a square-pyramidal coordination by the apically placed O atom of the DENA ligand, with a Cu - O distance of 2.4303(15)Å. In the two CB anions, the carboxylate groups are twisted relative to the attached benzene rings by 2.19(12) and 3.87(15)°, while the benzene rings are oriented at a dihedral angle of 5.52(8)°. The DENA ligands bridge adjacent Cu2+ ions, forming polymeric coordination chains running along the b axis. In the crystal, strong water-carboxylate O - H···O hydrogen bonds link adjacent chains into layers parallel to (10-1) and weak C - H···O hydrogen bonds further stabilize the crystal structure. The cyano group C and N atoms of one of the CB ligands are disordered over two sets of sites with equal occupancies. |
| Anahtar Kelimeler |
| crystal structure | coordination polymers | copper(II) benzoates | nicotinamide ligands |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Dergi Tarandığı Indeksler | ESCI: Emerging Sources Citation Index |
| Makale Dili | İngilizce |
| Basım Tarihi | 08-2016 |
| Cilt No | 72 |
| Sayı | 8 |
| Sayfalar | 1183 / 0 |
| Doi Numarası | 10.1107/S205698901601183X |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S205698901601183X |
