catena Poly diaquabis 4 formylbenzoato kO1 copper II mu pyrazine k2N N
Yazarlar (5)
Fatih Celik Kafkas Üniversitesi, Türkiye
Nefise Dilek Aksaray Üniversitesi, Türkiye
Nagihan Caylak Delibas
Sakarya Üniversitesi, Türkiye
Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hokelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
|
||
| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | Scopus, Thomson Reuters Emerging Sources Citation Index | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2014 |
| Kabul Tarihi | 27-11-2013 | Yayınlanma Tarihi | 07-12-2013 |
| Cilt / Sayı / Sayfa | 70 / 1 / – | DOI | 10.1107/S1600536813032297 |
| Makale Linki | https://journals.iucr.org/e/issues/2014/01/00/su2669/su2669.pdf | ||
| Özet |
| In the title polymeric compound, [Cu(C8H5O3)2(C4H4N2)(H2O)2]n, the CuII atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination sphere. In the equatorial plane, it is coordinated by two carboxylate O atoms of two symmetry-related monodentate formylbenzoate anions and by two N atoms of the bridging pyrazine ligand, which is bisected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water molecules. In the formylbenzoate anion, the carboxylate group is twisted away from the attached benzene ring by 6.2 (2)°, while the benzene and pyrazine rings are oriented at a dihedral angle of 68.91 (8)°. The pyrazine ligands bridge the CuII cations, forming polymeric chains running along the b-axis direction. Strong intramolecular O—H⋯O hydrogen bonds link the water molecules to the carboxylate O atoms. In the crystal, O—Hwater … |
| Anahtar Kelimeler |
Science Direct
catena Poly diaquabis 4 formylbenzoato kO1 copper II mu pyrazine k2N N
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |