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catena Poly diaquabis 4 formylbenzoato kO1 copper II mu pyrazine k2N N      
Yazarlar
Fatih Çelik
Kafkas Üniversitesi, Turkey
Nefise Dilek
Aksaray Üniversitesi, Turkey
Nagihan Çaylak Delibaş
Sakarya Üniversitesi, Turkey
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Özet
In the title polymeric compound, [Cu(C8H5O 3)2(C4H4N2)(H2O) 2]n , the CuII atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination sphere. In the equatorial plane, it is coordinated by two carboxylate O atoms of two symmetry-related monodentate formylbenzoate anions and by two N atoms of the bridging pyrazine ligand, which is bisected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water molecules. In the formylbenzoate anion, the carboxylate group is twisted away from the attached benzene ring by 6.2(2)°, while the benzene and pyrazine rings are oriented at a dihedral angle of 68.91(8)°. The pyrazine ligands bridge the Cu II cations, forming polymeric chains running along the b-axis direction. Strong intramolecular O-H⋯O hydrogen bonds link the water molecules to the carboxylate O atoms. In the crystal, O-Hwater⋯Owater hydrogen bonds link adjacent chains into layers parallel to the bc plane. The layers are linked via C-Hpyrazine⋯Oformyl hydrogen bonds, forming a three-dimensional network. There are also weak C-H⋯π interactions present.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler Scopus, Thomson Reuters Emerging Sources Citation Index
Makale Dili İngilizce
Basım Tarihi 01-2014
Cilt No 70
Sayı 1
Doi Numarası 10.1107/S1600536813032297
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
WoS 4
SCOPUS 6
catena Poly diaquabis 4 formylbenzoato kO1 copper II mu pyrazine k2N N

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