catena Poly aquabis 4 formylbenzoato k2O1 O1 cadmium mu pyrazine k2N N
Yazarlar (5)
Dr. Öğr. Üyesi Fatih Celik Kafkas Üniversitesi, Türkiye
Nefise Dilek
Aksaray Üniversitesi, Türkiye
Aksaray Üniversitesi, Türkiye
Nagihan Caylak Delibas
Sakarya Üniversitesi, Türkiye
Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hokelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | Scopus, Thomson Reuters Emerging Sources Citation Index | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2014 |
| Kabul Tarihi | 31-12-2013 | Yayınlanma Tarihi | 11-01-2014 |
| Cilt / Sayı / Sayfa | 70 / 2 / – | DOI | 10.1107/S1600536813035010 |
| Makale Linki | https://doi.org/10.1107/s1600536813035010 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| The polymeric title compound, [Cd(C8H5O3)2(C4H4N2)(H2O)]n, contains two 4-formylbenzoate (FB) anions, one pyrazine molecule and one coordinating water molecule; the FB anions act as bidentate ligands. The O atom, the aldehyde H atom and the benzene ring of one of the FB anions are disordered over two positions. The O atoms were freely refined [refined occupancy ratio 0.79 (2):0.21 (2)], while the aldehyde H atoms and the benzene ring atoms were refined with fixed occupancy ratios of 0.8:0.2 and 0.5:0.5, respectively. In the ordered FB anion, the carboxylate group is twisted away from the attached benzene ring (A) by 22.7 (8)°. In the disordered FB anion, the corresponding angles are 15.6 (10) and 11.4 (11)° for rings B and B′, respectively. Benzene rings A and B are oriented at a dihedral angle of 24.2 (7), A and B′ at 43.0 (8)°. The pyrazine ring makes dihedral angles of 67.5 (4), 89.6 (7 … |
| Anahtar Kelimeler |
| data-to-parameter ratio = 12.5 | disorder in main residue | mean σ(C-C) = 0.011 Å | R factor = 0.059 | single-crystal X-ray study | T = 294 K | wR factor = 0.144 |
Science Direct
catena Poly aquabis 4 formylbenzoato k2O1 O1 cadmium mu pyrazine k2N N
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 2 |
| Scopus | 2 |
| Google Scholar | 5 |