Crystal structure of catena poly di aqua bis 4 formyl benzoato O1 cobalt II pyrazine 2N N
Yazarlar (5)
Aşkın Gülçin Şefiye
Türkiye
Türkiye
Fatih Çelik Türkiye
Nefise Dilek Aksaray Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | Thomson Reuters Emerging Sources Citation Index | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2015 |
| Cilt / Sayı / Sayfa | 71 / 4 / 339–0 | DOI | 10.1107/S205698901500403X |
| Makale Linki | https://journals.iucr.org/e/issues/2015/04/00/wm5129/wm5129.pdf | ||
| Özet |
| In the title polymeric compound, [Co(C8H5O3)(2)(C4H4N2)(H2O)(2)](n), the Co-II atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination sphere. In the equatorial plane, it is coordinated by two carboxylate O atoms of two symmetry-related monodentate formylbenzoate anions and by two N atoms of two bridging pyrazine ligands. The latter are bisected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water molecules. In the formylbenzoate anion, the carboxylate group is twisted away from the attached benzene ring by 7.50 (8)degrees, while the benzene and pyrazine rings are oriented at a dihedral angle of 64.90 (4)degrees. The pyrazine ligands bridge the Co-II cations, forming linear chains running along the b-axis direction. Strong intramolecular O-H center dot center dot center dot O hydrogen bonds link the water molecules to … |
| Anahtar Kelimeler |
| crystal structure | cobalt(II) | transition metal complexes | benzoic acid derivatives | one-dimensional coordination polymer |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 2 |
| Google Scholar | 3 |