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Crystal structure of trans di aqua bis 4 cyano benzoato O bis nicotinamide N1 cobalt II       
Yazarlar
Aşkın Gülçin Şefiye
Türkiye
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Yılmaz Nayir Gamze
Türkiye
Çatak Çelik Raziye
Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Özet
In the title complex, [Co(C8H4NO2)2(C6H6N2O)2(H2O)2], the CoII atom is located on an inversion centre and is coordinated by two 4-cyanobenzoate (CNB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination sphere is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 22.11 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 89.98 (5)°. In the crystal, intermolecular N - H⋯O and O - H⋯O hydrogen bonds link the molecules, enclosing R22(8) and R44(8) ring motifs, forming layers parallel to (100). The layers are linked via C - H⋯O and C - H⋯N hydrogen bonds, resulting in a three-dimensional network. A weak C - H⋯π interaction is also observed.
Anahtar Kelimeler
crystal structure | cobalt(II) | transition metal complexes of benzoic acid and nicotinamide derivatives
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler Thomson Reuters Emerging Sources Citation Index
Makale Dili İngilizce
Basım Tarihi 05-2015
Cilt No 71
Sayı 5
Sayfalar 561 / 0
Doi Numarası 10.1107/S2056989015008270
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S2056989015008270