Crystal structure of tri aqua 4 cyano benzoato 2O O nicotinamide N1 zinc 4 cyano benzoate
Yazarlar (5)
Aşkın Gülçin Şafiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Yılmaz Nayir Gamze
Çatak Çelik Raziye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | Thomson Reuters Emerging Sources Citation Index | ||
| Makale Dili | İngilizce | Basım Tarihi | 06-2015 |
| Kabul Tarihi | 20-05-2015 | Yayınlanma Tarihi | 23-05-2015 |
| Cilt / Sayı / Sayfa | 71 / 6 / 684–0 | DOI | 10.1107/S2056989015009743 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S2056989015009743 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| The asymmetric unit of the title salt, [Zn(C8H4NO2)(C6H6N2O)(H2O)3](C8H4NO2), contains one complex cation and one 4-cyanobenzoate (CNB) counter-anion. The ZnII atom in the cation is coordinated by one 4-cyanobenzoate ligand, one nicotinamide (NA) ligand and three water molecules, the CNB anion thereby coordinating in a bidentate O,O′-mode through the carboxylate group. The latter, together with one water O atom and the N atom of the NA ligand, form a distorted square-planar arrangement, while the considerably distorted octahedral coordination sphere of the ZnII atom is completed by the two O atoms of additional water molecules in the axial positions. The dihedral angles between the planar carboxylate groups and the adjacent benzene rings in the two anions are 10.25 (10) and 5.89 (14)°. Intermolecular O—H⋯O hydrogen bonds link two of the coordinating water molecules to two free CNB … |
| Anahtar Kelimeler |
| crystal structure | zinc | transition metal complexes | benzoic acid nicotinamide |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 4 |