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Crystal structure of tetra kis 2 4 6 tri methyl benzoato 2O O bis nicotinamide N1 copper II       
Yazarlar
Aşkın Gülçin Şefiye
Türkiye
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özkaya Safiye
Türkiye
Nefise Dilek
Aksaray Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Özet
In the title binuclear CuII complex, [Cu2(C10H11O2)4(C6H6N2O)2], the two CuII cations [Cu···Cu = 2.5990 (5) Å] are bridged by four 2,4,6-trimethylbenzoate (TMB) anions. The four nearest O atoms around each CuII cation form distorted square-planar arrangements and the distorted square-pyramidal coordinations are completed by the pyridine N atoms of nicotinamide molecules at distances of 2.164 (2) and 2.165 (2) Å, respectively. The CuII cations are displaced by -0.2045 (3) and 0.2029 (3) Å from the corresponding planes formed by the nearest four O atoms. In the molecule, the dihedral angles between the planes of the benzene rings and the adjacent carboxylate groups are 80.6(2), 51.4(2), 24.4 (2) and 32.5 (2)°, while the planes of the pyridine rings are oriented at a dihedral angle of 11.28 (10)°. In the crystal, bifurcated N-H···O and weak C-H···O hydrogen bonds link the molecules, enclosing R22(8) and R44(8) ring motifs, into a three-dimensional network. The structure contains a solvent-accessible void of 72 Å3, but there is no solvent molecule located within this void. The crystal studied was an inversion twin refined with a minor component of 0.488 (8).
Anahtar Kelimeler
crystal structure | copper(II) complex | nicotinamide ligand | 2,4,6-trimethylbenzoate
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler Thomson Reuters Emerging Sources Citation Index
Makale Dili İngilizce
Basım Tarihi 08-2015
Cilt No 71
Sayı 8
Sayfalar 989 / 992
Doi Numarası 10.1107/S2056989015013882
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S2056989015013882
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Crystal structure of tetra kis 2 4 6 tri methyl benzoato 2O O bis nicotinamide N1 copper II

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