Diaquabis N N diethylnicotinamide kappa N 1 bis 4 ethylbenzoato kappa O cobalt II
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Ali Maraci
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Bariş Tercan
Karabük Üniversitesi, Türkiye
Karabük Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
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Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2011 |
| Kabul Tarihi | 15-04-2011 | Yayınlanma Tarihi | 22-04-2011 |
| Cilt / Sayı / Sayfa | 67 / 5 / – | DOI | 10.1107/S1600536811014188 |
| Makale Linki | https://journals.iucr.org/e/issues/2011/05/00/su2268/su2268.pdf | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| The title CoII complex, [Co(C9H9O2)2(C10H14N2O)2(H2O)2], contains two 4-ethylbenzoate (PEB), two monodentate diethylnicotinamide (DENA) ligands and two water molecules. The four O atoms in the equatorial plane around the CoII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intramolecular O—H⋯O hydrogen bonds link the water molecules to the carboxylate groups. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 4.52 (18) and 4.56 (18)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 7.76 (10) and 5.67 (13)°. In the crystal, intermolecular O—H⋯O hydrogen bonds link the molecules into chains propagating along [010]. C—H⋯O interactions and a π–π contact between the pyridine rings … |
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