Diaquabis(4-formylbenzoato-κO1)bis(nicotinamide-κN1)copper(II)
Yazarlar (4)
Doç. Dr. Mustafa SERTÇELİK Kafkas Üniversitesi, Türkiye
Nagihan Delibaş Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(Diğer hakemli uluslarası dergilerde yayınlanan tam makale)
|
||
| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | Scopus | ||
| Makale Dili | İngilizce | Basım Tarihi | 06-2012 |
| Cilt / Sayı / Sayfa | 68 / 7 / 290– | DOI | 10.1107/S1600536812028814 |
| Makale Linki | https://doi.org/10.1107/s1600536812028814 | ||
| Özet |
| In the title complex, [Cu(C8H5O3)2(C6H6N2O)2(H2O)2], the CuII cation is located on an inversion center and is coordinated by two 4-formylbenzoate (FB) anions, two nicotinamide (NA) ligands and two water molecules in an elongated distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 23.00 (10)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 85.34 (4)°. An intramolecular O—H⋯O hydrogen bond occurs between coordinating water molecule and the carboxylate group. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular network. A weak C—H⋯π interaction also occurs in the crystal. |
| Anahtar Kelimeler |
| Atıf Sayıları | |
| Google Scholar | 4 |
| Google Scholar | 13 |