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bis nicotinamide and bis N N diethyl nicotinamide p hydroxybenzoate complexes of Ni II Cu II and Zn II Spectrothermal studies       
Yazarlar
Hasan İçbudak
Ondokuz Mayıs Üniversitesi, Türkiye
Zerrin Heren
Ondokuz Mayıs Üniversitesi, Türkiye
Dursun Ali Köse
Hitit Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
The mixed-ligand p-hydroxybenzoate complexes of Ni(II), Cu(II) and Zn(II) with nicotinamide and N,N-diethylnicotinamide were synthesized and characterized by elemental analysis, magnetic susceptibility measurements and mass spectrometry. The thermal behavior of the complexes was studied by simultaneous TG, DTG and DTA methods in static air atmosphere. The infrared spectral characteristics of the complexes are also discussed. The complexes contain two water molecules, two p-hydroxybenzoato (p-hba) and two nicotinamide (na) (or diethylnicotinamide (dena)) ligands per formula unit. In these complexes, all ligands are coordinated to the metal ion as monodendate ligands. In Zn(II)-na and Cu(II)-dena complexes, the p-hydroxybenzoate behaves as bidentate chelating ligand through carboxylic oxygen atoms. The decomposition pathways and the stability of the complexes are interpreted in the terms of the structural data. The final decomposition products were found to be the respective metal oxides.
Anahtar Kelimeler
diethylnicotinamide | metal complexes | nicotinamide | p-hydroxybenzoato | thermal decomposition
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Dergi ISSN 1388-6150
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 01-2004
Cilt No 76
Sayı 3
Sayfalar 837 / 851
Doi Numarası 10.1023/B:JTAN.0000032269.12381.42