Synthesis and characterization of Bis N N diethylnicotinamide m hydroxybenzoate complexes of Co II Ni H Cu II and Zn II
Yazarlar (3)
D. A. Köse
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
A. Kaya Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Russian Journal of Coordination Chemistry Koordinatsionnaya Khimiya | ||
| Dergi ISSN | 1070-3284 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2007 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-06-2007 |
| Cilt / Sayı / Sayfa | 33 / 6 / 422–427 | DOI | 10.1134/S1070328407060073 |
| Makale Linki | https://link.springer.com/10.1134/S1070328407060073 | ||
| Özet |
| Four novel mixed-ligand complexes of Co(II), Ni(II), Cu(II), and Zn(II) with m-hydroxybenzoate (m-Hba) and N,N-diethylnicotinamide (Dena) were synthesized and characterized on the basis of elemental analysis, FT-IR spectroscopic study, and solid state UV-Vis spectrophotometric and magnetic-susceptibility data. The thermal behavior of the complexes was studied by combined TG-DTA methods in static air atmosphere, and the mass spectra were recorded. The Co(II), Ni(II), and Zn(II) complexes, except for the Cu(II) complex, contain two molecules of coordinated water, two m-Hba, and two Dena ligands per formula unit. In these complexes, the m-Hba and Dena behave as monodentate ligands via acidic oxygen and nitrogen of the pyridine ring. In the Cu(II) complex, the m-Hba is coordinated as monoanionic bidentate ligand through acidic oxygen and carbonyl oxygen. Dena is bonded with Cu2+ as monodentate … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
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