Synthesis and characterization of bis nicotinamide m hydroxybenzoate complexes of Co II Ni II Cu II and Zn II
Yazarlar (2)
D. A. Köse
Hacettepe Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Thermal Analysis and Calorimetry
Dergi ISSN 1388-6150 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2008
Kabul Tarihi Yayınlanma Tarihi 22-07-2008
Cilt / Sayı / Sayfa 93 / 2 / 509–514 DOI 10.1007/s10973-007-8712-5
Makale Linki http://link.springer.com/10.1007/s10973-007-8712-5
Özet
The mixed-ligand m-hydroxybenzoate complexes of Co(II), Ni(II), Cu(II) and Zn(II) with nicotinamide were synthesized and characterized. The chemical, FT IR and UV-vis spectrophotometric, thermal and mass spectral analyses, magnetic susceptibility measurements revealed that the compounds contain two water molecules, two m-hydroxybenzoate (m-hba) and two nicotinamide (na) ligands per formula unit. m-Hydroxybenzoate and nicotinamide ligands bind to the metal atoms monodentately through their acidic oxygen and pyridinic nitrogen atoms, respectively. The thermal decomposition pathways and the stability of the complexes are interpreted in the terms of the structural data.
Anahtar Kelimeler
M-hydroxybenzoate | Metal complexes | Nicotinamide | Thermal decomposition | Transition metals
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Google Scholar 140
Web of Science 94
Scopus 100
Synthesis and characterization of bis nicotinamide m hydroxybenzoate complexes of Co II Ni II Cu II and Zn II

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