Diaquabis 4 dimethylamino benzoato kappa O isonicotinamide kappa N 1 manganese II
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hakan Dal Anadolu Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Özgür Aybirdi
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2009
Kabul Tarihi 10-07-2009 Yayınlanma Tarihi 08-08-2009
Cilt / Sayı / Sayfa 65 / 9 / – DOI 10.1107/S1600536809027093
Makale Linki https://doi.org/10.1107/s1600536809027093
Özet
The title MnII complex, [Mn(C9H10NO2)2(C6H6N2O)(H2O)2], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water molecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial plane around the Mn atom form a highly distorted square-planar arrangement, while the distorted octahedral coordination geometry is completed by the N atom of the INA ligand and the O atom of the second water molecule in the axial positions. In the crystal structure, strong intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (010). Two weak C—H⋯π interactions are also found.
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