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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2009 |
| Cilt / Sayı / Sayfa | 65 / 9 / – | DOI | 10.1107/S1600536809027093 |
| Özet |
| The title MnII complex, [Mn(C9H10NO 2)2(C6H6N2O)(H 2O)2], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water molecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial plane around the Mn atom form a highly distorted square-planar arrangement, while the distorted octa-hedral coordination geometry is completed by the N atom of the INA ligand and the O atom of the second water mol-ecule in the axial positions. In the crystal structure, strong inter-molecular O - H⋯O, O - H⋯N and N - H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (010). Two weak C - H⋯π inter-actions are also found. © Hökelek et al. 2009. |
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