Yazarlar |
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
Hakan Dal
Anadolu Üniversitesi, Türkiye |
Mustafa Barış Tercan
Karabük Üniversitesi, Türkiye |
Aybirdi Özgür
Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Özet |
The title MnII complex, [Mn(C9H10NO 2)2(C6H6N2O)(H 2O)2], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water molecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial plane around the Mn atom form a highly distorted square-planar arrangement, while the distorted octa-hedral coordination geometry is completed by the N atom of the INA ligand and the O atom of the second water mol-ecule in the axial positions. In the crystal structure, strong inter-molecular O - H⋯O, O - H⋯N and N - H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (010). Two weak C - H⋯π inter-actions are also found. © Hökelek et al. 2009. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
Dergi ISSN | 2056-9890 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 09-2009 |
Cilt No | 65 |
Sayı | 9 |
Doi Numarası | 10.1107/S1600536809027093 |
Atıf Sayıları | |
WoS | 20 |
SCOPUS | 21 |