Diaquabis 4 methoxybenzoato kappa O bis nicotinamide kappa N 1 nickel II dihydrate
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hakan Dal
Anadolu Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Erdinç Tenlik
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2010 |
| Cilt / Sayı / Sayfa | 66 / 8 / – | DOI | 10.1107/S1600536810025985 |
| Özet |
| In the mononuclear title compound, [Ni(C8H7O 3)2(C6H6N2O) 2(H2O)2]·2H2O, the Ni II ion is located on a crystallographic inversion center. The asymmetric unit further contains one 4-methoxy-benzoate anion, one nicotinamide (NA) ligand and one coordinated and one uncoordinated water molecule; all ligands are monodentate. The four O atoms in the equatorial plane around the NiII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 7.2 (1)°, while the pyridine and benzene rings are oriented at a dihedral angle of 72.80 (4)°. An intra-molecular O - H⋯O hydrogen bond links the uncoordinated water molecule to one of the carboxylate groups. In the crystal structure, intermolecular O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
| Anahtar Kelimeler |
Science Direct
Diaquabis 4 methoxybenzoato kappa O bis nicotinamide kappa N 1 nickel II dihydrate
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 6 |
| SCOPUS | 6 |