Tetraaquabis isonicotinamide kappa N 1 cobalt II bis 4 formylbenzoate dihydrate
Yazarlar (5)
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Filiz Ylmaz Anadolu Üniversitesi, Türkiye
Bar Tercan Karabük Üniversitesi, Türkiye
Doç. Dr. Mustafa SERTÇELİK Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2009 |
| Cilt / Sayı / Sayfa | 65 / 9 / – | DOI | 10.1107/S1600536809033200 |
| Makale Linki | https://doi.org/10.1107/s1600536809033200 | ||
| Özet |
| The asymmetric unit of the crystal structure of the title complex, [Co(C6H6N2O)2(H2O)4](C8H5O3)2·2H2O, contains one-half of the complex cation with the CoII ion located on an inversion center, a 4-formylbenzoate (FB) counter-anion and an uncoordinated water molecule. The four O atoms in the equatorial plane around the CoII ion form a slightly distorted square-planar arrangement with an average Co—O bond length of 2.086 Å; the slightly distorted octahedral coordination is completed by the two N atoms of the isonicotinamide (INA) ligands at a slightly longer distance [2.1603 (14) Å] in the axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 5.93 (13)°, while the pyridine and benzene rings are oriented at a dihedral angle of 3.09 (6)°. In the crystal structure, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network … |
| Anahtar Kelimeler |
Science Direct
Tetraaquabis isonicotinamide kappa N 1 cobalt II bis 4 formylbenzoate dihydrate
| Atıf Sayıları | |
| Google Scholar | 17 |
| Web of Science | 8 |
| Scopus | 2 |