trans Diaquabis nicotinamide kappa N bis salicylato kappa O cobalt II
Yazarlar (4)
Şahin Onur
Büyükgüngör Orhan
Ali Köse Dursun
Necefoğlu Hacali
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION C | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2008 |
| Cilt / Sayı / Sayfa | – / 64 / 317– | DOI | – |
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| The title compound, [Co(C7H5O3)2(C6H6N2O)2(H2O)2], forms a three-dimensional hydrogen-bonded supramolecular structure. The CoII ion is in an octahedral coordination environment comprising two pyridyl N atoms, two carboxylate O atoms and two O atoms from water molecules. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds produce R22(8), R22(12) and R22(14) rings, which lead to two-dimensional chains. An extensive three-dimensional supramolecular network of C—H⋯O, N—H⋯O and O—H⋯O hydrogen bonds and C—H⋯π interactions is responsible for crystal structure stabilization. This study is an example of the construction of a supramolecular assembly based on hydrogen bonds in mixed-ligand metal complexes. |
| Anahtar Kelimeler |
