Yazarlar |
Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye |
Bar Tercan
Karabük Üniversitesi, Turkey |
Ertan Ahin
Atatürk Üniversitesi, Turkey |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
Özet |
The title compound, [Mn(C8H5O3) 2(C10H14N2O)2(H 2O)2], contains one MnII atom lying on an inversion centre, two 4-formyl-benzoate and two diethyl-nicotinamide ligands and two coordinated water mol-ecules. All ligands are monodentate. The four O atoms around the Mn atom form a slightly distorted equatorial plane, while the distorted octa-hedral coordination is completed by the two N atoms in the axial positions. An intra-molecular O - H⋯O hydrogen bond occurs in the complex. In the crystal structure, O - H⋯O hydrogen bonds link the mol-ecules through an R 2 2(16) ring motif, forming a one-dimensional chain along the a axis. The π-π contact between the pyridyl rings [centroid-centroid distance = 3.629 (2) Å] may further stabilize the structure. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
Dergi ISSN | 2056-9890 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 03-2009 |
Cilt No | 65 |
Sayı | 3 |
Doi Numarası | 10.1107/S1600536809006047 |
Atıf Sayıları | |
WoS | 8 |
SCOPUS | 8 |