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catena Poly triaquacobalt II mu 2 6 dioxo 1 2 3 6 tetrahydropyrimidine 4 carboxylato 2 1 72 hydrate        
Yazarlar
Onur Şahin
Ondokuz Mayis Üniversitesi, Turkey
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Turkey
Dursun Ali Köse
Hacettepe Üniversitesi, Turkey
Birgül Zümreoglu-Karan
Hacettepe Üniversitesi, Turkey
 Hacali NECEFOĞLU Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
The CoII ion in the title complex {[Co(C5H 2N2O4)(H2O)3]·1. 72H2O}n, has a distorted octahedral coordination geometry comprised of three water ligands, one deprotonated pyrimidine N atom and an adjacent carboxylate O atom of one orotate ligand. The sixth coordination site is occupied by an exocyclic O atom from a neighbouring orotate moiety, and through this interaction a helicoidal chain is formed. The molecules are linked by intramolecular Owater-H⋯O and intermolecular N-H⋯O and Owater-H⋯O hydrogen bonds, forming a three-dimensional network. © 2006 International Union of Crystallography.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Dergi ISSN 2053-2296
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 11-2006
Cilt No 62
Sayı 11
Doi Numarası 10.1107/S010827010603767X