catena Poly triaquacobalt II mu 2 6 dioxo 1 2 3 6 tetrahydropyrimidine 4 carboxylato 2 1 72 hydrate
       
Yazarlar (5)
Onur Şahin Ondokuz Mayis Üniversitesi, Türkiye
Orhan Büyükgüngör Ondokuz Mayis Üniversitesi, Türkiye
Dursun Ali Köse Hacettepe Üniversitesi, Türkiye
Birgül Zümreoglu-Karan Hacettepe Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section C Crystal Structure Communications
Dergi ISSN 0108-2701
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 11-2006
Cilt / Sayı / Sayfa 62 / 11 / – DOI 10.1107/S010827010603767X
Özet
The CoII ion in the title complex {[Co(C5H 2N2O4)(H2O)3]·1. 72H2O}n, has a distorted octahedral coordination geometry comprised of three water ligands, one deprotonated pyrimidine N atom and an adjacent carboxylate O atom of one orotate ligand. The sixth coordination site is occupied by an exocyclic O atom from a neighbouring orotate moiety, and through this interaction a helicoidal chain is formed. The molecules are linked by intramolecular Owater-H⋯O and intermolecular N-H⋯O and Owater-H⋯O hydrogen bonds, forming a three-dimensional network. © 2006 International Union of Crystallography.
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