Synthesis Spectral Thermal and Structural Study of Monoaquabis Acetylsalicylato kappa O bis Nicotinamide kappa N Copper II
Yazarlar (4)
Dursun Ali Kose Hacettepe Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Onur Sahin Ondokuz Mayis Üniversitesi, Türkiye
Orhan Buyukgungor Ondokuz Mayis Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Journal of Chemical Crystallography | ||
| Dergi ISSN | 1074-1542 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2011 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 31-08-2010 |
| Cilt / Sayı / Sayfa | 41 / 3 / 297–305 | DOI | 10.1007/s10870-010-9876-6 |
| Makale Linki | http://link.springer.com/10.1007/s10870-010-9876-6 | ||
| Özet |
| The compound has been formed by mononuclear [Cu(C9H7O4)2(C6H6N2O)2(H2O)] units in which the metal ion as well as the water ligand lies on a twofold symmetry axis, so that only one acetylsalicylate ligand and one nicotinamide ligand are independent. The distortion from ideal five-coordinate geometries can be described best by the degree of trigonality τ. For a regular square-pyramidal (SQP) geometry the trigonality parameter is 0 and for a trigonal–bipyramidal (TBP) structure it increases to 1. The copper coordination geometry is that of a square pyramid (τ = 0.23), with the N atoms from nicotinamide ligands and the bonded carboxylate O atoms from acetylsalicylate ligands defining the quasi-planar square base. The apical site is occupied by the aqua ligand, a bond which coincides with the twofold symmetry axis and is thus exactly perpendicular to the basal plane. The thermal decomposition takes place … |
| Anahtar Kelimeler |
| Acetylsalicylate | Crystal structure | Mixed ligand complexes | Nicotinamide | Thermal decomposition | Transition metal complexes |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 20 |
| Web of Science | 16 |
| Scopus | 14 |