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Synthesis Spectral Thermal and Structural Study of Monoaquabis Acetylsalicylato kappa O bis Nicotinamide kappa N Copper II       
Yazarlar
Dursun Ali Kose
Hacettepe Üniversitesi, Turkey
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Onur Şahin
Ondokuz Mayis Üniversitesi, Turkey
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Turkey
Özet
The compound has been formed by mononuclear [Cu(C 9 H 7 O 4 ) 2 (C 6 H 6 N 2 O) 2 (H 2 O)] units in which the metal ion as well as the water ligand lies on a twofold symmetry axis, so that only one acetylsalicylate ligand and one nicotinamide ligand are independent. The distortion from ideal five-coordinate geometries can be described best by the degree of trigonality τ. For a regular square-pyramidal (SQP) geometry the trigonality parameter is 0 and for a trigonal-bipyramidal (TBP) structure it increases to 1. The copper coordination geometry is that of a square pyramid (τ = 0.23), with the N atoms from nicotinamide ligands and the bonded carboxylate O atoms from acetylsalicylate ligands defining the quasi-planar square base. The apical site is occupied by the aqua ligand, a bond which coincides with the twofold symmetry axis and is thus exactly perpendicular to the basal plane. The thermal decomposition takes place in four steps: removing of moisture, dehydration of aqua ligand, the elimination of the nicotinamide (na) ligand and the decomposition of acetyl-groups and oxidation of salicylate ion ligands. In complex, all ligands are coordinated to the metal ion as monodendate. The IR spectra of the intermediate products showed similar results. © 2010 Springer Science+Business Media, LLC.
Anahtar Kelimeler
Mixed ligand complexes | Thermal decomposition | Transition metal complexes | Crystal structure | Nicotinamide | Acetylsalicylate
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
Dergi ISSN 1074-1542
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 03-2011
Cilt No 41
Sayı 3
Sayfalar 297 / 305
Doi Numarası 10.1007/s10870-010-9876-6