Crystal structure of trans diaquabis 3 aminobenzoato O bis nicotinamide N cobalt II
     
Yazarlar (2)
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Analytical Sciences
Dergi ISSN 0910-6340 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 10-1999
Cilt / Sayı / Sayfa 15 / 10 / 1043–1044 DOI 10.2116/analsci.15.1043
Özet
Crystal Structure of trans-Diaquabis(3-aminobenzoato-O)- bis(nicotinamide-N)cobalt(II) Page
1 Nicotinamide (NA) is one form of niacin. The deficiency of this vitamin leads to a loss of
copper from the body, known as pellagra disease. The nicotinic acid derivative, N,N-diethylnicotinamide
(DENA), is an important respiratory stimulant. The title compound was prepared by dissolving
CoSO4·7(H2O) (2.81 g, 0.01 mol) and NA (2.44 g, 0.02 mol) in water (75 ml) and
sodium-3-aminobenzoate (3.18 g, 0.02 mol) in water (25 ml) and then adding the solutions.
The mixture was set aside for crystallization at ambient temperature for a few days. A structure
determination of the title compound was undertaken in order to determine the ligand properties
of NA and benzoate ligands, and to compare the coordination geometries when the NA
ligands are substituted for water in complexes [Co(p-O2NC6H4COO)2(H2O)4]1 (I) and [Co(p-…
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