catena Poly aquabis 3 chlorobenzoato k2O O cadmium mu N N diethylnicotinamide k2N1 O
Yazarlar (5)
Nihat Bozkurt
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Prof. Dr. Tuncay Tunc Aksaray Üniversitesi, Türkiye
Nagihan Caylak Delibas
Sakarya Üniversitesi, Türkiye
Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hokelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SCOPUS dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 Dergi Bilgileri (2013) | ||
| Dergi Tarandığı Indeksler | Scopus | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2013 |
| Kabul Tarihi | 16-07-2013 | Yayınlanma Tarihi | 20-07-2013 |
| Cilt / Sayı / Sayfa | 69 / 8 / – | DOI | 10.1107/S160053681301965X |
| Makale Linki | https://doi.org/10.1107/s160053681301965x | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| In the crystal of the title CdII polymeric complex, [Cd(C7H4ClO2)2(C10H14N2O)(H2O)]n, the CdII cation is chelated by two chlorobenzoate anions and coordinated by two N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted NO6 pentagonal–bipyramidal geometry. The CdII cations are bridged by the pyridine N atom and carbonyl O atom of the DENA ligand to form a polymeric chain running along the b axis. Intermolecular O—H⋯O hydrogen bonds between coordinating water molecules and carboxylate groups link adjacent chains into layers parallel to the bc plane. π–π contacts between benzene rings [shortest centroid–centroid distance = 3.912 (2) Å] further stabilizes the crystal structure. In the molecule, weak C—H⋯O hydrogen bonds occur between the pyridine ring and carboxylate groups; the dihedral angles between the carboxylate groups and adjacent benzene rings are 4.6 (3 … |
| Anahtar Kelimeler |
| data-to-parameter ratio = 20.0 | meanω(C - C) = 0.006 A ° | Rfactor = 0.046 | single-crystal X-ray study | T = 296 K | wRfactor = 0.093 |
Science Direct
catena Poly aquabis 3 chlorobenzoato k2O O cadmium mu N N diethylnicotinamide k2N1 O
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 1 |