| Yazarlar |
Nihat Bozkurt
Kafkas Üniversitesi, Turkey |
|
Tuncay Tunç
Aksaray Üniversitesi, Turkey |
|
Nagihan Çaylak Delibaş
Sakarya Üniversitesi, Turkey |
Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
| Özet |
| The title compound, [Cu(C7H4ClO2)2(C10H14N2O)2(H2O)], has twofold symmetry with the CuII cation and the O atom of the coordinating water molecule located on the axis. The CuII cation is coordinated by two carboxylate O atoms of chlorobenzoate (CB) anions, two N atoms of N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted N2O3 square-pyramidal geometry. The benzene and pyridine rings are oriented at a dihedral angle of 82.51 (6)°. In the anionic ligand, the carboxylate group is twisted away from the attached benzene ring by 12.85 (11)°. In the crystal, O - H⋯O hydrogen bonds between the coordinating water molecule and the carboxyl group link the complex molecules into supramolecular chains running along the c-axis direction. |
| Anahtar Kelimeler |
| data-to-parameter ratio = 27.8 | meanω(C - C) = 0.003 A ° | Rfactor = 0.032 | single-crystal X-ray study | T = 296 K | wRfactor = 0.086 |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Dergi ISSN | 2056-9890 |
| Dergi Tarandığı Indeksler | Scopus |
| Makale Dili | İngilizce |
| Basım Tarihi | 08-2013 |
| Cilt No | 69 |
| Sayı | 8 |
| Doi Numarası | 10.1107/S1600536813018989 |
| Atıf Sayıları | |
| WoS | 3 |
| SCOPUS | 4 |
| ResearchGate | 1 |
