| Makale Türü |
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | Scopus | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2013 |
| Cilt / Sayı / Sayfa | 69 / 8 / – | DOI | 10.1107/S1600536813018989 |
| Özet |
| The title compound, [Cu(C7H4ClO2)2(C10H14N2O)2(H2O)], has twofold symmetry with the CuII cation and the O atom of the coordinating water molecule located on the axis. The CuII cation is coordinated by two carboxylate O atoms of chlorobenzoate (CB) anions, two N atoms of N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted N2O3 square-pyramidal geometry. The benzene and pyridine rings are oriented at a dihedral angle of 82.51 (6)°. In the anionic ligand, the carboxylate group is twisted away from the attached benzene ring by 12.85 (11)°. In the crystal, O - H⋯O hydrogen bonds between the coordinating water molecule and the carboxyl group link the complex molecules into supramolecular chains running along the c-axis direction. |
| Anahtar Kelimeler |
| data-to-parameter ratio = 27.8 | meanω(C - C) = 0.003 A ° | Rfactor = 0.032 | single-crystal X-ray study | T = 296 K | wRfactor = 0.086 |
| Atıf Sayıları | |
| WoS | 3 |
| SCOPUS | 4 |
| ResearchGate | 1 |