Aquabis 3 chlorobenzoato kO bis N N diethylnicotinamide kN copper II
     
Yazarlar (5)
Nihat Bozkurt Kafkas Üniversitesi, Türkiye
Tuncay Tunç Aksaray Üniversitesi, Türkiye
Nagihan Çaylak Delibaş Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SCOPUS dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler Scopus
Makale Dili İngilizce Basım Tarihi 08-2013
Cilt / Sayı / Sayfa 69 / 8 / – DOI 10.1107/S1600536813018989
Özet
The title compound, [Cu(C7H4ClO2)2(C10H14N2O)2(H2O)], has twofold symmetry with the CuII cation and the O atom of the coordinating water molecule located on the axis. The CuII cation is coordinated by two carboxylate O atoms of chlorobenzoate (CB) anions, two N atoms of N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted N2O3 square-pyramidal geometry. The benzene and pyridine rings are oriented at a dihedral angle of 82.51 (6)°. In the anionic ligand, the carboxylate group is twisted away from the attached benzene ring by 12.85 (11)°. In the crystal, O - H⋯O hydrogen bonds between the coordinating water molecule and the carboxyl group link the complex molecules into supramolecular chains running along the c-axis direction.
Anahtar Kelimeler
data-to-parameter ratio = 27.8 | meanω(C - C) = 0.003 A ° | Rfactor = 0.032 | single-crystal X-ray study | T = 296 K | wRfactor = 0.086