| Yazarlar |
Nihat Bozkurt
Kafkas Üniversitesi, Turkey |
|
Tuncay Tunç
Aksaray Üniversitesi, Turkey |
|
Nagihan Çaylak Delibaş
Sakarya Üniversitesi, Turkey |
Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
| Özet |
| In the title centrosymmetric binuclear CuII complex, [Cu2(C7H4ClO2)4(C10H14N2O)2], the two CuII cations [Cu⋯Cu = 2.6314 (4) Å] are bridged by four 3-chlorobenzoate (CB) anions. The four carboxylate O atoms around each CuII cation form a distorted square-planar arrangement, the distorted square-pyramidal coordination geometry being completed by the pyridine N atom of the N,N-diethylnicotinamide (DENA) molecule. The dihedral angle between the benzene ring and the carboxylate group is 4.49 (11)° in one of the independent CB ligands and 12.00 (10)° in the other. The benzene rings of the independent CB ligands are oriented at a dihedral angle of 84.13 (6)°. In the crystal, weak C - H⋯O hydrogen bonds link the binuclear complex molecules into supramolecular chains running along [101]. |
| Anahtar Kelimeler |
| data-to-parameter ratio = 16.7 | meanω(C - C) = 0.003 A ° | Rfactor = 0.031 | single-crystal X-ray study | T = 296 K | wRfactor = 0.083 |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Dergi ISSN | 2056-9890 |
| Dergi Tarandığı Indeksler | Scopus |
| Makale Dili | İngilizce |
| Basım Tarihi | 08-2013 |
| Cilt No | 69 |
| Sayı | 8 |
| Doi Numarası | 10.1107/S1600536813017881 |
| Atıf Sayıları | |
| WoS | 1 |
| SCOPUS | 1 |
| Google Scholar | 64 |
| ResearchGate | 53 |
