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Di mu nicotinamide k2N1 O k2O N1 bis aquabis 3 chlorobenzoato k2O O cadmium       
Yazarlar
Nihat Bozkurt
Nefise Dilek
Nagihan Çaylak Delibaş
Hacali Necefoğlu
Tuncer Hökelek
Özet
In the centrosymmetric dinuclear title compound, [Cd2(C7H4ClO2)4(C6H6N2O) 2(H2O)2], the CdII atom is coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, four O atoms from two 3-chlorobenzoate ligands and one water molecule in an irregular geometry. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 6.98 (12) and 2.42 (13)°, while the benzene rings are oriented at a dihedral angle of 4.33 (6)°. Intermolecular O - H...O, N - H...O and weak C - H...O hydrogen bonds link the molecules into a three-dimensional network. π-π interactions, indicated by short centroid-centroid distances [3.892 (1) Å between the pyridine rings and 3.683 (1) Å between the benzene rings] further stabilize the structure.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SCOPUS dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler Scopus
Makale Dili İngilizce
Basım Tarihi 01-2013
Cilt No 69
Sayfalar 389 /
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
WoS 5
SCOPUS 5
Google Scholar 10

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