Di mu nicotinamide k2N1 O k2O N1 bis aquabis 3 chlorobenzoato k2O O cadmium
       
Yazarlar (5)
Nihat Bozkurt Kafkas Üniversitesi, Türkiye
Nefise Dilek Aksaray Üniversitesi, Türkiye
Nagihan Çaylak Delibaş Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SCOPUS dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler Scopus
Makale Dili İngilizce Basım Tarihi 07-2013
Cilt / Sayı / Sayfa 69 / 7 / – DOI 10.1107/S1600536813015948
Özet
In the centrosymmetric dinuclear title compound, [Cd2(C7H4ClO2)4(C6H6N2O) 2(H2O)2], the CdII atom is coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, four O atoms from two 3-chlorobenzoate ligands and one water molecule in an irregular geometry. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 6.98 (12) and 2.42 (13)°, while the benzene rings are oriented at a dihedral angle of 4.33 (6)°. Intermolecular O - H...O, N - H...O and weak C - H...O hydrogen bonds link the molecules into a three-dimensional network. π-π interactions, indicated by short centroid-centroid distances [3.892 (1) Å between the pyridine rings and 3.683 (1) Å between the benzene rings] further stabilize the structure.
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