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Di mu nicotinamide k2N1 O k2O N1 bis aquabis 3 chlorobenzoato k2O O cadmium        
Yazarlar
Nihat Bozkurt
Kafkas Üniversitesi, Turkey
Nefise Dilek
Aksaray Üniversitesi, Turkey
Nagihan Çaylak Delibaş
Sakarya Üniversitesi, Turkey
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Özet
In the centrosymmetric dinuclear title compound, [Cd2(C7H4ClO2)4(C6H6N2O) 2(H2O)2], the CdII atom is coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, four O atoms from two 3-chlorobenzoate ligands and one water molecule in an irregular geometry. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 6.98 (12) and 2.42 (13)°, while the benzene rings are oriented at a dihedral angle of 4.33 (6)°. Intermolecular O - H...O, N - H...O and weak C - H...O hydrogen bonds link the molecules into a three-dimensional network. π-π interactions, indicated by short centroid-centroid distances [3.892 (1) Å between the pyridine rings and 3.683 (1) Å between the benzene rings] further stabilize the structure.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SCOPUS dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler Scopus
Makale Dili İngilizce
Basım Tarihi 07-2013
Cilt No 69
Sayı 7
Doi Numarası 10.1107/S1600536813015948