Yazarlar |
Nihat Bozkurt
|
Nefise Dilek
|
Nagihan Çaylak Delibaş
|
Hacali Necefoğlu
|
Tuncer Hökelek
|
Özet |
In the centrosymmetric dinuclear title compound, [Cd2(C7H4ClO2)4(C6H6N2O) 2(H2O)2], the CdII atom is coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, four O atoms from two 3-chlorobenzoate ligands and one water molecule in an irregular geometry. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 6.98 (12) and 2.42 (13)°, while the benzene rings are oriented at a dihedral angle of 4.33 (6)°. Intermolecular O - H...O, N - H...O and weak C - H...O hydrogen bonds link the molecules into a three-dimensional network. π-π interactions, indicated by short centroid-centroid distances [3.892 (1) Å between the pyridine rings and 3.683 (1) Å between the benzene rings] further stabilize the structure. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E |
Dergi ISSN | 1600-5368 |
Dergi Tarandığı Indeksler | Scopus |
Makale Dili | İngilizce |
Basım Tarihi | 01-2013 |
Cilt No | 69 |
Sayfalar | 389 / |