| Yazarlar (5) |
Nihat Bozkurt
Kafkas Üniversitesi, Türkiye |
|
Nefise Dilek
Aksaray Üniversitesi, Türkiye |
|
Nagihan Çaylak Delibaş
Sakarya Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
| Özet |
| The molecule of the title CuII complex, [Cu(C7H4ClO2)2(C6H6N2O) 2], contains two 3-chlorobenzoate (CB) and two nicotinamide (NA) ligands; the CB act as bidentate ligands, while the NA are monodentate ligands. The resulting CuN2O4 coordination polyhedron is a considerably distorted octahedron. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 17.92 (12) and 24.69 (16)°, while the two benzene rings and the two pyridine rings are oriented at dihedral angles of 52.20 (8) and 1.56 (6)°. In the crystal, N - H...N and C - H...O hydrogen bonds link the molecules into a three-dimensional network. The π-π contact between the benzene rings [centroid-centroid distance = 3.982 (2) Å] may further stabilize the crystal structure. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayınlanan tam makale |
| Dergi Adı |
Acta Crystallographica Section E Structure Reports Online
|
| Dergi ISSN | 1600-5368 |
| Dergi Tarandığı Indeksler | Scopus |
| Makale Dili | İngilizce |
| Basım Tarihi | 07-2013 |
| Cilt No | 69 |
| Sayı | 7 |
| Doi Numarası | 10.1107/S1600536813014694 |
| Atıf Sayıları | |
| WoS | 3 |
| SCOPUS | 2 |
