Diaquabis 3 chlorobenzoato kO bis nicotinamide kN1 cobalt II
Yazarlar (5)
Öznur Dincel Karabük Üniversitesi, Türkiye
Bariş Tercan
Karabük Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SCOPUS dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368 Dergi Bilgileri (2013)
Dergi Tarandığı Indeksler Scopus
Makale Dili İngilizce Basım Tarihi 01-2013
Kabul Tarihi 20-02-2013 Yayınlanma Tarihi 28-02-2013
Cilt / Sayı / Sayfa 69 / 3 / – DOI 10.1107/S1600536813004984
Makale Linki https://journals.iucr.org/e/issues/2013/03/00/xu5678/xu5678.pdf
UAK Araştırma Alanları
Anorganik Kimya
Özet
In the title complex, [Co(C7H4ClO2)2(C6H6N2O)2(H2O)2], the CoII atom is located on an inversion center and is coordinated by two 3-chlorobenzoate (CB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 9.14 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 82.18 (8)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the molecules into a two-dimensional network lying parallel to (101). π–π stacking between parallel pyridine rings of adjacent molecules [centroid–centroid distance = 3.7765 (8) Å] further stabilizes the crystal structure.
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Diaquabis 3 chlorobenzoato kO bis nicotinamide kN1 cobalt II

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