| Yazarlar |
Nihat Bozkurt
|
|
Nefise Dilek
|
|
Nagihan Çaylak Delibaş
|
|
Hacali Necefoğlu
|
|
Tuncer Hökelek
|
| Özet |
| In the title complex, [Co(C7H4ClO2) 2(C6H6N2O)2(H 2O)2], the CoII atom is located on an inversion center and is coordinated by two 3-chlorobenzoate (CB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 9.14 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 82.18 (8)°. In the crystal, N - H⋯O and O - H⋯O hydrogen bonds link the molecules into a two-dimensional network lying parallel to (101). π-π stacking between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.7765 (8) Å] further stabilizes the crystal structure. © Bozkurt et al. 2013. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E |
| Dergi ISSN | 1600-5368 |
| Dergi Tarandığı Indeksler | Scopus |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2013 |
| Cilt No | 69 |
| Sayfalar | 349 / |
