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Diaquabis 2 chlırobenzoato kO bis nicotinamide kN1 cobalt II     
Yazarlar
Nihat Bozkurt
Kafkas Üniversitesi, Turkey
Nefise Dilek
Aksaray Üniversitesi, Turkey
Nagihan Çaylak Delibaş
Sakarya Üniversitesi, Turkey
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Özet
In the title complex, [Co(C7H4ClO2) 2(C6H6N2O)2(H 2O)2], the CoII atom is located on an inversion center and is coordinated by two 3-chlorobenzoate (CB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 9.14 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 82.18 (8)°. In the crystal, N - H⋯O and O - H⋯O hydrogen bonds link the molecules into a two-dimensional network lying parallel to (101). π-π stacking between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.7765 (8) Å] further stabilizes the crystal structure. © Bozkurt et al. 2013.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SCOPUS dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler Scopus
Makale Dili İngilizce
Basım Tarihi 06-2013
Cilt No 69
Sayı 6
Doi Numarası 10.1107/S160053681301458X
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Diaquabis 2 chlırobenzoato kO bis nicotinamide kN1 cobalt II

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