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Bis mu 4 metylbenzoato k3O O O k3O O O bis aqua 4 metylbenzoato k2O O nicotinamide kN1 cadmium       
Yazarlar
Öznur Dincel
Karabük Üniversitesi, Turkey
Bariş Tercan
Karabük Üniversitesi, Turkey
Efdal Çimen
Kafkas Üniversitesi, Turkey
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Özet
In the dinuclear centrosymmetric title compound, [Cd2(C8H7O2)4(C6H6N2O) 2(H2O)2], the CdII ion is chelated by two carboxylate groups from 4-methylbenzoate anions, and is further coordinated by one nicotinamide and one water molecule; a carboxylate O atom from an adjacent 4-methylbenzoate anion bridges to the CdII ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, intermolecular O-H⋯O, N-H⋯O and weak C-H⋯O hydrogen bonds link the molecules into a three-dimensional network. The methylbenzene moiety of one bridging 4-methylbenzoate anion is disordered over two orientations of equal occupancy.
Anahtar Kelimeler
data-to-parameter ratio = 16.3 | disorder in main residue | mean ω(C-C) = 0.003 Å | R factor = 0.019 | single-crystal X-ray study | T = 100 K | wR factor = 0.048
Makale Türü Özgün Makale
Makale Alt Türü SCOPUS dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler Scopus
Makale Dili İngilizce
Basım Tarihi 12-2012
Cilt No 68
Sayı 12
Doi Numarası 10.1107/S1600536812047046