Bis mu 4 metylbenzoato k3O O O k3O O O bis aqua 4 metylbenzoato k2O O nicotinamide kN1 cadmium
      
Yazarlar (5)
Öznur Dincel Karabük Üniversitesi, Türkiye
Bariş Tercan Karabük Üniversitesi, Türkiye
Dr. Öğr. Üyesi Efdal ÇİMEN Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SCOPUS dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler Scopus
Makale Dili İngilizce Basım Tarihi 12-2012
Cilt / Sayı / Sayfa 68 / 12 / – DOI 10.1107/S1600536812047046
Özet
In the dinuclear centrosymmetric title compound, [Cd2(C8H7O2)4(C6H6N2O) 2(H2O)2], the CdII ion is chelated by two carboxylate groups from 4-methylbenzoate anions, and is further coordinated by one nicotinamide and one water molecule; a carboxylate O atom from an adjacent 4-methylbenzoate anion bridges to the CdII ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, intermolecular O-H⋯O, N-H⋯O and weak C-H⋯O hydrogen bonds link the molecules into a three-dimensional network. The methylbenzene moiety of one bridging 4-methylbenzoate anion is disordered over two orientations of equal occupancy.
Anahtar Kelimeler
data-to-parameter ratio = 16.3 | disorder in main residue | mean ω(C-C) = 0.003 Å | R factor = 0.019 | single-crystal X-ray study | T = 100 K | wR factor = 0.048