| Makale Türü |
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | Scopus | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2012 |
| Cilt / Sayı / Sayfa | 68 / 12 / – | DOI | 10.1107/S1600536812047046 |
| Özet |
| In the dinuclear centrosymmetric title compound, [Cd2(C8H7O2)4(C6H6N2O) 2(H2O)2], the CdII ion is chelated by two carboxylate groups from 4-methylbenzoate anions, and is further coordinated by one nicotinamide and one water molecule; a carboxylate O atom from an adjacent 4-methylbenzoate anion bridges to the CdII ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, intermolecular O-H⋯O, N-H⋯O and weak C-H⋯O hydrogen bonds link the molecules into a three-dimensional network. The methylbenzene moiety of one bridging 4-methylbenzoate anion is disordered over two orientations of equal occupancy. |
| Anahtar Kelimeler |
| data-to-parameter ratio = 16.3 | disorder in main residue | mean ω(C-C) = 0.003 Å | R factor = 0.019 | single-crystal X-ray study | T = 100 K | wR factor = 0.048 |