Diaquabis 2 iodobenzoato kO bis nikotinamide kN1 copper II
       
Yazarlar (4)
Ömüir Aydn
Kafkas Üniversitesi, Türkiye
Nagihan Çaylak Delibaş
Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SCOPUS dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler Scopus
Makale Dili İngilizce Basım Tarihi 09-2012
Cilt / Sayı / Sayfa 68 / 9 / – DOI 10.1107/S1600536812034587
Makale Linki https://journals.iucr.org/e/issues/2012/09/00/xu5599/xu5599.pdf
Özet
In the title complex, [Cu(C7H4IO2) 2(C6H6N2O)2(H 2O)2], the CuII cation is located on an inversion center and is coordinated by two monodentate 2-iodo-benzoate (IB) anions, two nicotinamide (NA) ligands and two water molecules in a distorted octahedral coordination geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 32.12 (14)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 82.02 (5)°. The coordinating water molecule links with the carboxylate group via an intramolecular O - H⋯O hydrogen bond. In the crystal, N - H⋯O, O - H⋯O and weak C - H⋯O hydrogen bonds link the molecules into a three-dimensional supra-molecular network.
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