Diaquabis 4 formylbenzoato kO1 bis nicotinamide kN1 copper II

SERTÇELİK, MUSTAFA; Deliba, Nagihan Çaylak; NECEFOĞLU, HACALİ; Hökelek, Tuncer

doi:10.1107/S1600536812028814

Diaquabis 4 formylbenzoato kO1 bis nicotinamide kN1 copper II

Yazarlar (4)

Doç. Dr. Mustafa SERTÇELİK Kafkas Üniversitesi, Türkiye

Nagihan Çaylak Deliba
Sakarya Üniversitesi, Türkiye

Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye

Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SCOPUS dergilerinde yayınlanan tam makale)
Dergi Adı	Acta Crystallographica Section E Structure Reports Online
Dergi ISSN	1600-5368
Dergi Tarandığı Indeksler	Scopus
Makale Dili	İngilizce	Basım Tarihi	01-2012
Kabul Tarihi	25-06-2012	Yayınlanma Tarihi	30-06-2012
Cilt / Sayı / Sayfa	68 / 7 / –	DOI	10.1107/S1600536812028814
Makale Linki	https://doi.org/10.1107/s1600536812028814
UAK Araştırma Alanları	Anorganik Kimya

Özet

In the title complex, [Cu(C8H5O3) 2(C6H6N2O)2(H 2O)2], the Cu^II cation is located on an inversion center and is coordinated by two 4-formylbenzoate (FB) anions, two nicotinamide (NA) ligands and two water molecules in an elongated distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 23.00 (10)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 85.34 (4)°. An intramolecular O - H⋯O hydrogen bond occurs between coordinating water molecule and the carboxylate group. In the crystal, N - H⋯O, O - H⋯O and weak C - H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular network. A weak C - H⋯π interaction also occurs in the crystal. © 2012 International Union of Crystallography.

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Diaquabis 4 formylbenzoato kO1 bis nicotinamide kN1 copper II

Diaquabis 4 formylbenzoato kO1 bis nicotinamide kN1 copper II

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