| Yazarlar |
Ömür Aydın
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|
Nagihan Çaylak Delibaş
|
|
Hacali Necefoğlu
|
|
Tuncer Hökelek
|
| Özet |
| In the title complex, [Co(C 7H 4IO 2) 2(C 6H 6N 2O) 2(H 2O) 2], the Co II cation is located on an inversion center and is coordinated by two monodentate 2-iodo-benzoate (IB) anions, two nicotin-amide (NA) ligands and two water mol-ecules. The four O atoms in the equatorial plane around the Co II cation form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 22.3 (3)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 84.59 (13)°. Intra-molecular O-H⋯O hydrogen bonding occurs between the carboxyl-ate group and coordinated water mol-ecule. In the crystal, N-H⋯O, O-H⋯O and weak C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular network. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E |
| Dergi ISSN | 1600-5368 |
| Dergi Tarandığı Indeksler | Scopus |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2012 |
| Cilt No | 68 |
| Sayfalar | 521 / |
