Diaquabis 2 iodobenzoato kO bis Nicotinamide kN cobalt II
Yazarlar (4)
Ömür Aydn
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Nagihan Çaylak Deliba
Sakarya Üniversitesi, Türkiye
Sakarya Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SCOPUS dergilerinde yayınlanan tam makale)
|
||
| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | Scopus | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2012 |
| Kabul Tarihi | 27-03-2012 | Yayınlanma Tarihi | 31-03-2012 |
| Cilt / Sayı / Sayfa | 68 / 4 / – | DOI | 10.1107/S160053681201330X |
| Makale Linki | https://doi.org/10.1107/s160053681201330x | ||
| UAK Araştırma Alanları |
Anorganik Kimya
|
||
| Özet |
| In the title complex, [Co(C7H4IO2)2(C6H6N2O)2(H2O)2], the CoII cation is located on an inversion center and is coordinated by two monodentate 2-iodobenzoate (IB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane around the CoII cation form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 22.3 (3)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 84.59 (13)°. Intramolecular O—H⋯O hydrogen bonding occurs between the carboxylate group and coordinated water molecule. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular network. |
| Anahtar Kelimeler |
Science Direct
Diaquabis 2 iodobenzoato kO bis Nicotinamide kN cobalt II
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |