| Yazarlar |
Ömür Aydn
Kafkas Üniversitesi, Turkey |
|
Nagihan Çaylak Deliba
Sakarya Üniversitesi, Turkey |
Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
| Özet |
| In the title complex, [Co(C 7H 4IO 2) 2(C 6H 6N 2O) 2(H 2O) 2], the Co II cation is located on an inversion center and is coordinated by two monodentate 2-iodo-benzoate (IB) anions, two nicotin-amide (NA) ligands and two water mol-ecules. The four O atoms in the equatorial plane around the Co II cation form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 22.3 (3)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 84.59 (13)°. Intra-molecular O-H⋯O hydrogen bonding occurs between the carboxyl-ate group and coordinated water mol-ecule. In the crystal, N-H⋯O, O-H⋯O and weak C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular network. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Dergi Tarandığı Indeksler | Scopus |
| Makale Dili | İngilizce |
| Basım Tarihi | 04-2012 |
| Cilt No | 68 |
| Sayı | 4 |
| Doi Numarası | 10.1107/S160053681201330X |
| Atıf Sayıları | |
| WoS | 7 |
| SCOPUS | 7 |
| Google Scholar | 13 |
