| Yazarlar |
Ömür Aydn
Kafkas Üniversitesi, Turkey |
|
Nagihan Çaylak Deliba
Sakarya Üniversitesi, Turkey |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
| Özet |
| In the centrosymmetric binuclear title complex, [Cu 2(C 7H 4IO 2) 4(H 2O) 2], the two Cu II ions [Cu⋯Cu = 2.6009 (5) Å] are bridged by four 2-iodo-benzoate (IB) ligands. The four nearest O atoms around each Cu II ion form a distorted square-planar arrangement, the distorted square-pyramidal coordination being completed by the O atom of the water mol-ecule at a distance of 2.1525 (16) Å. The dihedral angle between the benzene ring and the carboxyl-ate group is 25.67 (13)° in one of the independent IB ligands and 6.44 (11)° in the other. The benzene rings of the two independent IB ligands are oriented at a dihedral angle of 86.61 (7)°. In the crystal, O-H⋯O inter-actions link the mol-ecules into a two-dimensional network. π-π contacts between the benzene rings [centroid-centroid distances = 3.810 (2) and 3.838 (2) Å] may further stabilize the structure. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Dergi Tarandığı Indeksler | Scopus |
| Makale Dili | İngilizce |
| Basım Tarihi | 04-2012 |
| Cilt No | 68 |
| Sayı | 4 |
| Doi Numarası | 10.1107/S1600536812010367 |
| Atıf Sayıları | |
| WoS | 4 |
| SCOPUS | 5 |
| Google Scholar | 9 |
