| Yazarlar |
Ibrahim Göker Zaman
Kafkas Üniversitesi, Turkey |
|
Nagihan Çaylak Delibaş
Sakarya Üniversitesi, Turkey |
Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
| Özet |
| The asymmetric unit of the title compound, [Ni(C 6H 6N 2O) 2(H 2O) 4](C 7H 5O 3) 2·4H 2O, contains one-half of the complex cation with the Ni II ion located on an inversion center, a 3-hydroxybenzoate counter-anion and two uncoordinated water molecules. Four water O atoms in the equatorial plane around the Ni II ion [Ni - O = 2.052 (2) and 2.079 (2) Å] form a slightly distorted squareplanar arrangement, which is completed up to a distorted octahedron by the two N atoms [Ni - N = 2.075 (3) Å] from two isonicotinamide ligands. In the anion, the carboxyl-ate group is twisted from the attached benzene ring by 8.8 (3)°. In the crystal, a three-dimensional hydrogen-bonding network, formed by classical O - H⋯O and N - H⋯O hydrogen bonds, consolidates the crystal packing, which also exhibits π-π interactions between the benzene and pyridine rings, with centroid-centroid distances of 3.455 (2) and 3.621 (2) Å, respectively. |
| Anahtar Kelimeler |
| data-to-parameter ratio = 14.5 | mean σ(C-C) = 0.004 Å | R factor = 0.051 | single-crystal X-ray study | T = 100 K | wR factor = 0.157 |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 02-2012 |
| Cilt No | 68 |
| Sayı | 2 |
| Doi Numarası | 10.1107/S1600536812002218 |
| Atıf Sayıları | |
| WoS | 3 |
| SCOPUS | 3 |
| ResearchGate | 8 |
