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trans Tetraaquabis isonicotinamide kappa N 1 nickel II bis 3 hydroxybenzoate tetrahydrate      
Yazarlar
Ibrahim Göker Zaman
Kafkas Üniversitesi, Turkey
Nagihan Çaylak Delibaş
Sakarya Üniversitesi, Turkey
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Özet
The asymmetric unit of the title compound, [Ni(C 6H 6N 2O) 2(H 2O) 4](C 7H 5O 3) 2·4H 2O, contains one-half of the complex cation with the Ni II ion located on an inversion center, a 3-hydroxybenzoate counter-anion and two uncoordinated water molecules. Four water O atoms in the equatorial plane around the Ni II ion [Ni - O = 2.052 (2) and 2.079 (2) Å] form a slightly distorted squareplanar arrangement, which is completed up to a distorted octahedron by the two N atoms [Ni - N = 2.075 (3) Å] from two isonicotinamide ligands. In the anion, the carboxyl-ate group is twisted from the attached benzene ring by 8.8 (3)°. In the crystal, a three-dimensional hydrogen-bonding network, formed by classical O - H⋯O and N - H⋯O hydrogen bonds, consolidates the crystal packing, which also exhibits π-π interactions between the benzene and pyridine rings, with centroid-centroid distances of 3.455 (2) and 3.621 (2) Å, respectively.
Anahtar Kelimeler
data-to-parameter ratio = 14.5 | mean σ(C-C) = 0.004 Å | R factor = 0.051 | single-crystal X-ray study | T = 100 K | wR factor = 0.157
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 02-2012
Cilt No 68
Sayı 2
Doi Numarası 10.1107/S1600536812002218