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Aquabis 4 fluorobenzoato kappa O bis nicotinamide kappa N 1 copper II nicotinamide hemisolvate trihydrate       
Yazarlar
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Vijdan Öztürk
Kafkas Üniversitesi, Turkey
Vedat Adigüzel
Kafkas Üniversitesi, Turkey
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Özet
The asymmetric unit of the title compound, [Cu(C 7H 4FO 2) 2-(C 6H 6N 2O) 2(H 2O)]·0.5C 6H 6N 2O·3H 2O, contains two aquabis(4-fluorobenzoato)bis(nicotinamide)copper(II) molecules, one nicotinamide solvent molecule and six water molecules. The Cu II ion is coordinated by two O atoms from two 4-fluorobenzoate ligands, two N atoms from two nicotinamide ligands and one water O atom in a distorted square-pyramidal geometry. In the crystal, O-H···O, O- H···N and N-H···O hydrogen bonds consolidate the crystal packing, which also exhibits π-π interactions between the aromatic rings [centroid-centroid distances 3.692(2)-3.794(2) Å].
Anahtar Kelimeler
Data-to-parameter ratio = 16.9 | Mean σ(C-C) = 0.006 Å | R factor = 0.063 | Single-crystal X-ray study | T = 100 K | wR factor = 0.160
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 01-2012
Cilt No 68
Sayı 1
Doi Numarası 10.1107/S1600536811053116