Diaquabis 4 bromobenzoato kappa O bis N N diethylnicotinamide kappa N 1 manganese II
    
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Vijdan Öztürk Kafkas Üniversitesi, Türkiye
Doç. Dr. Vedat ADIGÜZEL Kafkas Üniversitesi, Türkiye
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 09-2011
Cilt / Sayı / Sayfa 67 / 9 / – DOI 10.1107/S1600536811031412
Özet
In the crystal structure of the title Mn II complex, [Mn(C 7H 4BrO2) 2(C 10H 14N 2O) 2(H 2O) 2], the Mn II cation is located on an inversion center and coordinated by two diethylnicotinamide (DENA) ligands, two 4-bromobenzoate (PBB) anions and two water molecules in a distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 3.25 (14)°. In the molecule, the pyridine ring and the benzene ring are oriented at a dihedral angle of 77.24 (5)°. In the crystal, intermolecular C - H⋯O hydrogen bonds link the molecules into a twodimensional network. Weak intermolecular C - H⋯O hydrogen bonds and π-π interactions between the pyridine rings of neighbouring molecules [centroidcentroid distance = 3.537 (1) Å] further consolidate the crystal packing.
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