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Diaquabis 4 bromobenzoato kappa O bis N N diethylnicotinamide kappa N 1 manganese II     
Yazarlar
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Vijdan Öztürk
Kafkas Üniversitesi, Turkey
Vedat Adigüzel
Kafkas Üniversitesi, Turkey
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Özet
In the crystal structure of the title Mn II complex, [Mn(C 7H 4BrO2) 2(C 10H 14N 2O) 2(H 2O) 2], the Mn II cation is located on an inversion center and coordinated by two diethylnicotinamide (DENA) ligands, two 4-bromobenzoate (PBB) anions and two water molecules in a distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 3.25 (14)°. In the molecule, the pyridine ring and the benzene ring are oriented at a dihedral angle of 77.24 (5)°. In the crystal, intermolecular C - H⋯O hydrogen bonds link the molecules into a twodimensional network. Weak intermolecular C - H⋯O hydrogen bonds and π-π interactions between the pyridine rings of neighbouring molecules [centroidcentroid distance = 3.537 (1) Å] further consolidate the crystal packing.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 09-2011
Cilt No 67
Sayı 9
Doi Numarası 10.1107/S1600536811031412
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Diaquabis 4 bromobenzoato kappa O bis N N diethylnicotinamide kappa N 1 manganese II

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