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Diaquabis 4 bromobenzoato kappa O bis N N diethylnicotinamide kappa N 1 copper II     
Yazarlar
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Vijdan Öztürk
Kafkas Üniversitesi, Turkey
Vedat Adigüzel
Kafkas Üniversitesi, Turkey
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Özet
The title Cu II complex, [Cu(C 7H 4BrO2) 2(C 10H 14N 2O) 2(H 2O) 2], contains two 4-bromobenzoate (PBB), two diethylnicotinamide (DENA) monodentate ligands and two water molecules. The four O atoms in the equatorial plane around the Cu II ion form a slightly distorted squareplanar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of the DENA ligands in the axial positions. Intramolecular O - H⋯O hydrogen bonds link the water molecules to the carboxylate groups. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 3.1 (3) and 3.74 (17)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 6.81 (10) and 3.38 (12)°. In the crystal, intermolecular O - H⋯O hydrogen bonds link the molecules into double chains along the b axis. C - H⋯O interactions are also observed. π-π contacts between pyridine rings [centroidcentroid distance = 3.485 (2) Å] may further stabilize the crystal structure.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 09-2011
Cilt No 67
Sayı 9
Doi Numarası 10.1107/S1600536811034787